Synthesis, Characterization and Application of β-Cyclodextrin/Imidazolium Based Dicationic Ionic Liquid Supported on Silica Gel as a Novel Catalyst in Hantzsch Condensation Reaction

被引：9
|
作者：
Moheiseni, Fatemeh [1 ,2 ]
Kiasat, Ali Reza [3 ]
Badri, Rashid [1 ,2 ]
机构：
[1] Islamic Azad Univ, Dept Chem, Ahvaz Branch, Ahwaz, Iran
[2] Islamic Azad Univ, Dept Chem, Khuzestan Sci & Res Branch, Ahwaz, Iran
[3] Shahid Chamran Univ Ahvaz, Coll Sci, Dept Chem, Ahwaz 6135743169, Iran
来源：
POLYCYCLIC AROMATIC COMPOUNDS | 2021年 / 41卷 / 05期
关键词：
beta-Cyclodextrin; dicationic ionic liquid supported on silica gel; Huntzsch reaction; monotosyl-beta-cyclodextrin; multicomponents reaction; beta CD; Im](OTs)2-Silica; ONE-POT SYNTHESIS; POLYHYDROQUINOLINE DERIVATIVES; EFFICIENT SYNTHESIS; MULTICOMPONENT SYNTHESIS; ONE-STEP; 1,4-DIHYDROPYRIDINES; FACILE; DIHYDROPYRIDINES; SYSTEMS; ESTERS;
D O I：
10.1080/10406638.2019.1650784
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Regarding the green chemistry's goals, ionic liquids (ILs) open a way to introduce amazing and efficient media for different reactions. Therefore, in the present study, a feasible protocol for the preparation of beta-cyclodextrin/imidazolium based dicationic ionic liquid and its supported on silica gel, [beta CD/Im](OTs)(2)-Silica are presented. Ability of this eco-friendly microvessel and host ionic liquid system in the one-pot three-components Hantzsch condensation reaction of arylaldehydes, ethylacetoacetate or dimedone and ammonium acetate are also described. The mild and easy reaction conditions, utilization of a catalyst with high catalytic activity and good reusability, and simple work-up procedure, makes this method as an interesting option for the facile and efficient synthesis of 1,4-dihydropyridine and polyhydroquinoline derivatives.
引用
收藏
页码：1094 / 1106
页数：13
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