Hydrogen production by aqueous phase reforming of phenol over Ni/ZSM-5 catalysts

被引：24
|
作者：
Yan, Beibei [1 ,2 ]
Li, Wanqing [1 ]
Tao, Junyu [1 ]
Xu, Ningge [1 ]
Li, Xiangping [3 ]
Chen, Guanyi [4 ]
机构：
[1] Tianjin Univ, Sch Environm Sci & Engn, Tianjin 300072, Peoples R China
[2] Tianjin Univ, China Petr & Chem Ind Federat, Key Lab Biomass Based Oil & Gas, Tianjin 300072, Peoples R China
[3] China Australia Ctr Sustainable Urban Dev, Tianjin 300072, Peoples R China
[4] Tibet Univ, Sch Sci, 36 Jiangsu St, Lhasa 850012, Tibet Autonomou, Peoples R China
来源：
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2017年 / 42卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Aqueous phase reforming; Phenol; Ni/ZSM-5; Si/Al molar ratio; Hydrogen production; ACETIC-ACID; BIO-OIL; ETHYLENE-GLYCOL; MODEL COMPOUNDS; NI; ZSM-5; GASOLINE; SORBITOL; ZEOLITE; ETHANOL;
D O I：
10.1016/j.ijhydene.2016.12.013
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrogen production from biomass in particular bio-oils appears interesting as bio-oils is easy to transport and storage with high conversion towards hydrogen. Phenol as presentation of lignin-derived bio-oils was chosen in this paper and was studied under aqueous phase reforming (APR) reaction using Nickel-based catalysts with ZSM-5 as support. The catalysts were synthesized by incipient wetness impregnation, and their physical and chemical properties were characterized by XRD, NH3-TPD, H-2-TPR, SEM, TEM and N-2 adsorption-desorption. Ni/ZSM-5 was studied with different Si/Al molar ratio and different Ni content on APR of phenol. The reactant concentration, reaction pressure and temperature were also evaluated. Ni/ZSM-5 with Si/Al molar ratio of 25 and nickel content of 16% exhibited the highest catalytic activity. Hydrogen production were maximized over the temperature of 240 degrees C, reaction pressure of 4 MPa and the phenol concentration of 0.2 mol/L. (C) 2016 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.
引用
收藏
页码：6674 / 6682
页数：9
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