Experimental and theoretical studies of paracetamol as a copper corrosion inhibitor

被引:14
|
作者
Tasic, Zaklina Z. [1 ]
Mihajlovic, Marija B. Petrovic [1 ]
Radovanovic, Milan B. [1 ]
Simonovic, Ana T. [1 ]
Antonijevic, Milan M. [1 ]
机构
[1] Univ Belgrade, Tech Fac Bor, VJ 12,POB 50, Bor 19210, Serbia
关键词
Paracetamol; Potassium sorbate; Copper; Synthetic acid rain solution; Protection; MILD-STEEL; POTASSIUM SORBATE; SULFURIC-ACID; DERIVATIVES; PROTECTION; DISPOSAL; BEHAVIOR; DRUG; RAIN; METRONIDAZOLE;
D O I
10.1016/j.molliq.2020.114817
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The utilization of copper as a material in various fields is well known. In such environments as a synthetic acid rain solution, various aggressive ions can be found that negatively affect the characteristics of copper, i.e. lead to its dissolution. The most common way to protect copper from dissolving is to use inhibitors. Therefore, in this paper, the possibility of expired paracetamol for preventing the corrosion of copper in a synthetic acid rain solution was investigated. The results obtained by electrochemical methods showed the resistance of copper to corrosion in the presence of paracetamol. Additionally, binary system of paracetamol and potassium sorbate showed higher inhibition efficiency (97%) in regard to paracetamol (96.3%). Furthermore, the calculated quantum chemical parameters as well ae Gibbs free energy confirmed the inhibitory ability of paracetamol achieved by adsorption on the copper surface. (C) 2020 Elsevier B.V. All rights reserved.
引用
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页数:9
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