Methanolic trimethylamine mediated Baylis-Hillman reaction

被引:0
|
作者
Basavaiah, D [1 ]
Rao, AJ [1 ]
Krishnamacharyulu, M [1 ]
机构
[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
关键词
Baylis-Hillman reaction; methanolic trimethylamine; methyl acrylate; acrylonitrile; acrolein;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Application of methanolic trimethylamine, the tertiary amine containing minimum number of carbon atoms with lowest possible molecular weight, for mediating the Baylis-Hillman coupling of various aldehydes with activated olefins viz. methyl acrylate, acrylonitrile and acrolein is described.
引用
收藏
页码:136 / 145
页数:10
相关论文
共 50 条
  • [31] Octanol-accelerated Baylis-Hillman reaction
    Park, Kwang-Su
    Kim, Jinyoung
    Choo, Hyunah
    Chong, Youhoon
    SYNLETT, 2007, (03) : 395 - 398
  • [32] Sulpholane - A new solvent for the Baylis-Hillman reaction
    Krishna, PR
    Manjuvani, A
    Kannan, V
    Sharma, GVM
    TETRAHEDRON LETTERS, 2004, 45 (06) : 1183 - 1185
  • [33] A synthesis of captopril through a Baylis-Hillman reaction
    Feltrin, MP
    Almeida, WP
    SYNTHETIC COMMUNICATIONS, 2003, 33 (07) : 1141 - 1146
  • [34] A novel modified Baylis-Hillman reaction of propiolate
    Matsuya, Y
    Hayashi, K
    Nemoto, H
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (03) : 646 - 647
  • [35] Miceller media accelerated Baylis-Hillman reaction
    Pawar, Balu
    Padalkar, Vikas
    Phatangare, Kiran
    Nirmalkar, Sudhakar
    Chaskar, Atul
    CATALYSIS SCIENCE & TECHNOLOGY, 2011, 1 (09) : 1641 - 1644
  • [36] Zinc mediated propenylation of Baylis-Hillman acetates
    Srihari, P.
    Singh, Ashutosh Pratap
    Basak, A. K.
    Yadav, J. S.
    TETRAHEDRON LETTERS, 2007, 48 (34) : 5999 - 6001
  • [37] Reaction of Baylis-Hillman Adducts with Fluorinated Silanes
    Zemtsov, Artem A.
    Levin, Vitalij V.
    Dilman, Alexander D.
    Struchkova, Marina I.
    Belyakov, Pavel A.
    Tartakovsky, Vladimir A.
    Hu, Jinbo
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2010, 2010 (35) : 6779 - 6785
  • [38] Organocatalyzed Baylis-Hillman reaction: an enantioselective approach
    Thorat, Prashant B.
    Goswami, Santosh V.
    Khade, Bhimrao C.
    Bhusare, Sudhakar R.
    TETRAHEDRON-ASYMMETRY, 2012, 23 (17) : 1320 - 1325
  • [39] Amine-catalyzed Baylis-Hillman reaction
    Cui, PL
    Wang, C
    Ma, JJ
    Zhang, YQ
    Gao, YJ
    Zang, XH
    Zhang, DN
    Zhou, X
    Zhang, HY
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2005, 25 (07) : 763 - 770
  • [40] The first successful intermolecular Heck reaction of Baylis-Hillman adducts:: synthesis of β-aryl substituted Baylis-Hillman adducts
    Kim, Jeong Mi
    Kim, Ko Hoon
    Kim, Taek Hyeon
    Kim, Jae Nyoung
    TETRAHEDRON LETTERS, 2008, 49 (20) : 3248 - 3251