Rare-earth N, N′-diarylformamidinate complexes

被引：49
|
作者：
Deacon, Glen B. [1 ]
Hossain, Md Elius [2 ]
Junk, Peter C. [2 ]
Salehisaki, Mehdi [2 ]
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[2] James Cook Univ, Coll Sci & Engn, Townsville, Qld 4811, Australia
来源：
COORDINATION CHEMISTRY REVIEWS | 2017年 / 340卷
基金：
澳大利亚研究理事会;
关键词：
Lanthanoids; Lanthanoid(II); Lanthanoid(III); Lanthanoid(IV); Formamidinates; ISOPRENE POLYMERIZATION; COORDINATION CHEMISTRY; TISHCHENKO REACTION; ACTIVATION; REACTIVITY; LIGANDS; METALS; CARBODIIMIDES; SAMARIUM(II); REDUCTION;
D O I：
10.1016/j.ccr.2017.02.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N, N'-bis(aryl) forma midinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：247 / 265
页数：19
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