Rare-earth N, N′-diarylformamidinate complexes

被引：49
|
作者：
Deacon, Glen B. [1 ]
Hossain, Md Elius [2 ]
Junk, Peter C. [2 ]
Salehisaki, Mehdi [2 ]
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
[2] James Cook Univ, Coll Sci & Engn, Townsville, Qld 4811, Australia
来源：
COORDINATION CHEMISTRY REVIEWS | 2017年 / 340卷
基金：
澳大利亚研究理事会;
关键词：
Lanthanoids; Lanthanoid(II); Lanthanoid(III); Lanthanoid(IV); Formamidinates; ISOPRENE POLYMERIZATION; COORDINATION CHEMISTRY; TISHCHENKO REACTION; ACTIVATION; REACTIVITY; LIGANDS; METALS; CARBODIIMIDES; SAMARIUM(II); REDUCTION;
D O I：
10.1016/j.ccr.2017.02.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This comprehensive review covers the progress of rare earth chemistry with formamidinate ligands to date. The ligands involved offer varying steric and electronic effects and focus on the N, N'-bis(aryl) forma midinates. Synthetic pathways to divalent, trivalent and tetravalent complexes, their structural aspects, reactivity and potential applications in catalysis are extensively discussed. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码：247 / 265
页数：19
相关论文
共 50 条
  • [1] Synthesis and characterization of the rare-earth chloride complexes with N, N,N′,N′-tetramethylmalonamide
    Kravchuk, Dmytro, V
    Wilson, Richard E.
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2024, 332
  • [2] MAGNETIC AND SPECTRAL BEHAVIOR OF RARE-EARTH COMPLEXES OF N,N'-DIMETHYL HYDRAZINE
    AGARWAL, RK
    SHARMA, MBL
    SRIVASTAVA, AK
    [J]. ACTA CHIMICA HUNGARICA-MODELS IN CHEMISTRY, 1986, 122 (3-4): : 277 - 283
  • [3] RARE-EARTH PICOLINATE AND PICOLINATE-N-OXIDE COMPLEXES
    MANNING, PG
    [J]. CANADIAN JOURNAL OF CHEMISTRY, 1966, 44 (12): : 1471 - &
  • [4] PYRIDINE-N-OXIDE COMPLEXES OF RARE-EARTH BROMIDES
    SIVAPULLAIAH, PV
    SOUNDARARAJAN, S
    [J]. REVUE ROUMAINE DE CHIMIE, 1977, 22 (11-1) : 1493 - 1497
  • [5] THERMAL-ANALYSIS OF RARE-EARTH COMPLEXES OF N-PHENYLBENZOHYDROXAMATE
    AGRAWAL, YK
    [J]. THERMOCHIMICA ACTA, 1980, 38 (02) : 153 - 155
  • [6] PYRIDINE-N-OXIDE COMPLEXES OF RARE-EARTH BROMIDES AND CHLORIDES
    SIVAPULLAIAH, PV
    SOUNDARARAJAN, S
    [J]. BULLETIN DES SOCIETES CHIMIQUES BELGES, 1981, 90 (02): : 147 - 153
  • [7] 4-PICOLINE-N-OXIDE COMPLEXES OF RARE-EARTH BROMIDES
    SIVAPULLAIAH, PV
    SOUNDARARAJAN, S
    [J]. INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1977, 13 (07): : 291 - 295
  • [8] 3-PICOLINE-N-OXIDE COMPLEXES OF RARE-EARTH BROMIDES
    SIVAPULLAIAH, PV
    SOUNDARARAJAN, S
    [J]. MONATSHEFTE FUR CHEMIE, 1976, 107 (04): : 871 - 878
  • [9] 2-PICOLINE-N-OXIDE COMPLEXES OF RARE-EARTH BROMIDES
    SIVAPULLAIAH, PV
    SOUNDARARAJAN, S
    [J]. JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1976, 38 (07): : 1402 - 1403
  • [10] 2-PICOLINE-N-OXIDE COMPLEXES OF RARE-EARTH CHLORIDES
    SIVAPULLAIAH, PV
    SOUNDARARAJAN, S
    [J]. CURRENT SCIENCE, 1976, 45 (20): : 711 - 712
12345