A novel synthesis of hierarchical porous carbons from resol by potassium acetate activation for high performance supercapacitor electrodes

被引:31
|
作者
Zhang, Jinliang [1 ,3 ]
Zhang, Wenfeng [2 ,3 ]
Zhang, Hao [2 ,3 ]
Pang, Jie [1 ,3 ]
Cao, Gaoping [2 ,3 ]
Han, Minfang [1 ]
Yang, Yusheng [2 ,3 ]
机构
[1] China Univ Min & Technol Beijing, Sch Chem & Environm Engn, Beijing 100083, Peoples R China
[2] Res Inst Chem Def, Beijing 100091, Peoples R China
[3] Beijing Key Lab Adv Chem Energy Storage Technol &, Beijing 100091, Peoples R China
关键词
Resol; Porous carbon; Potassium acetate; Supercapacitors; ORDERED MESOPOROUS CARBON; OXYGEN REDUCTION; ENERGY-STORAGE; ADSORPTION; NITROGEN; MICROSPHERES; MICROPORES; GRAPHENE; SURFACE;
D O I
10.1016/j.jallcom.2017.04.066
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel strategy for the synthesis of hierarchical porous carbons (HPCs) from resol by potassium acetate activation for advanced supercapacitor electrodes was reported. The resultant HPCs with a high specific surface area up to 1201 m(2) g(-1) as a supercapacitor electrode exhibits a high specific capacitance of 226 F g(-1) at 0.05 A g(-1). Besides, the electrode shows high rate capability with 62.4% retention from 0.05 to 20 A g(-1). Moreover, it demonstrates good cyclic stability, showing a high capacitance retention of 97.1% over 5000 charge-discharge cycles at 2.0 A g(-1). The facile, efficient and template-free synthesis strategy for novel 3D-HPCs may promote commercial application of HPCs in the fields of supercapacitors. (C) 2017 Published by Elsevier B.V.
引用
收藏
页码:76 / 81
页数:6
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