Cobalt(II)-Catalyzed C-H Amination of Arenes with Simple Alkylamines

被引：96
|
作者：
Zhang, Lin-Bao [1 ]
Zhang, Shou-Kun [1 ]
Wei, Donghui [1 ]
Zhu, Xinju [1 ]
Hao, Xin-Qi [1 ]
Su, Jian-Hang [1 ]
Niu, Jun-Long [1 ]
Song, Mao-Ping [1 ]
机构：
[1] Zhengzhou Univ, Coll Chem & Mol Engn, Zhengzhou 450001, Peoples R China
来源：
ORGANIC LETTERS | 2016年 / 18卷 / 06期
关键词：
CATALYZED DIRECT AMINATION; N BOND FORMATION; INTRAMOLECULAR AMINATION; INTERMOLECULAR AMINATION; ACID-DERIVATIVES; C(SP(3))-H BONDS; TERMINAL ALKYNES; AMIDATION; ACTIVATION; ANILINES;
D O I：
10.1021/acs.orglett.6b00241
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new method of cobalt-catalyzed amination of arylamides with simple alkylamines is reported through C(sp(2))-H bond functionalization. For the first time, inexpensive cobalt is exploited as the catalyst in the amination of C(sp(2))-H bond using simple alkylamines.
引用
收藏
页码：1318 / 1321
页数：4
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