Metal substitution reaction in the cluster (mu-H)(2)Fe-3(mu(3)-Se)(CO)(9) .2. Crystal and molecular structure of [FeW2(mu(3)-Se)(CO)(7)-Cp(2)] and [FeMoW(mu(3)-Se)(CO)(7)Cp(2)] (Cp=eta(5)-C5H5)

被引：15

作者：

Konchenko, SN

Virovets, AV

Tkachev, SV

Podberezskaya, NV

机构：

[1] Institute of Inorganic Chemistry, Siberian Division of RAS, Acad. Lavrentyev str. 3

来源：

POLYHEDRON | 1997年 / 16卷 / 04期

关键词：

iron; molybdenum; selenium; tungsten; heterometallic clusters; synthesis; crystal and molecular structure;

D O I：

10.1016/0277-5387(96)00267-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The sequential substitution of two Fe(CO)(3) groups in [(mu-H)(2)Fe-3(mu(3)-Se) (CO)(9)] with isolobal fragments CpW(CO)(2) (the first stage) and CpMo(CO), (the second stage) has been shown to result in the title heterotrimetal cluster [FeMoW(mu(3)-Se) (CO)(7)Cp(2)]. Its structure and the structure of its [FeW2(mu(3)-Se)(CO)(7)Cp(2)] analog obtained previously have been determined by X-ray analysis. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：707 / 712

页数：6

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