One-Pot Synthesis of Indoles and Aniline Derivatives from Nitroarenes under Hydrogenation Condition with Supported Gold Nanoparticles

被引：139

作者：

Yamane, Yoshihiro ^{[1
,2
]}

Liu, Xiaohao ^{[1
,2
]}

Hamasaki, Akiyuki ^{[1
,2
]}

Ishida, Tamao ^{[2
,3
]}

Haruta, Masatake ^{[2
,3
]}

Yokoyama, Takushi ^{[1
,2
]}

Tokunaga, Makoto ^{[1
,2
]}

机构：

[1] Kyushu Univ, Grad Sch Sci, Dept Chem, Fukuoka 8128581, Japan

[2] CREST, JST Japan Sci & Technol Cooperat, Tokyo, Japan

[3] Tokyo Metropolitan Univ, Dept Appl Chem, Grad Sch Urban Environm Sci, Tokyo 1920397, Japan

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 22期

关键词：

AROMATIC NITRO-COMPOUNDS; CHEMOSELECTIVE HYDROGENATION; CASCADE REACTIONS; CATALYSTS; REDUCTION; NITROAROMATICS; HYDROAMINATION; OLEFINS; AMINES;

D O I：

10.1021/ol902061j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

One-pot sequences of hydrogenation/hydroamination to form Indoles from (2-nitroaryl)alkynes and hydrogenation/reductive amination to form aniline derivatives from nitroarenes and aldehydes were catalyzed by Au nanoparticles supported on Fe2O3. Nitro group selective hydrogenations and successive reactions were efficiently catalyzed under the conditions.

引用

页码：5162 / 5165

页数：4

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