An improved one-pot procedure for the synthesis of alkynes from aldehydes

被引:2
|
作者
Muller, S [1 ]
Liepold, B [1 ]
Roth, GJ [1 ]
Bestmann, HJ [1 ]
机构
[1] UNIV ERLANGEN NURNBERG,INST ORGAN CHEM,D-91054 ERLANGEN,GERMANY
关键词
aldehydes; alkynes; dimethyl-1-diazo-2-oxopropylphosphonate;
D O I
暂无
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The transformation of aldehydes to terminal alkynes can be achieved with the reagent dimethyl-1-diazo-2-oxopropylphosphonate 2. The one-pot procedure allows the isolation of the products under very mild conditions in good to excellent yields without requiring low temperatures or inert gas techniques and avoiding the use of strong bases.
引用
收藏
页码:521 / &
页数:3
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