Potential energy surface of the Rydberg states of the NO molecule in an intense IR radiation field

被引：1

作者：

Malyshev, N. S. ^{[1
]}

Kuverova, V. V. ^{[1
]}

Ozerov, G. K. ^{[1
]}

Golubkov, G. V. ^{[1
]}

Golubkov, M. G. ^{[1
]}

Adamson, S. O. ^{[2
]}

机构：

[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia

[2] Moscow MV Lomonosov State Univ, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B | 2017年 / 11卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

Rydberg states of the NO molecule; interaction with valence and dissociative configurations; external laser field; radiation collision matrix; resonance states; CONFIGURATION-INTERACTION CALCULATIONS; BASIS-SET; PLUS O;

D O I：

10.1134/S1990793117010250

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

A method taking into account valence (non-Rydberg) and dissociative configurations has been developed for calculation of potential energy surfaces of the NO molecule in an intense IR radiation field. The resonance rovibronic structure of the Rydberg molecule-laser field quantum system has been analyzed within the steady-state formalism of the radiation collision matrix using multi-channel quantum defect theory. Special conditions for field control of predissociation involving intermediate Rydberg and valence states have been formulated.

引用

页码：77 / 82

页数：6

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