Potential energy surface of the Rydberg states of the NO molecule in an intense IR radiation field

被引：1
|
作者：
Malyshev, N. S. [1 ]
Kuverova, V. V. [1 ]
Ozerov, G. K. [1 ]
Golubkov, G. V. [1 ]
Golubkov, M. G. [1 ]
Adamson, S. O. [2 ]
机构：
[1] Russian Acad Sci, Semenov Inst Chem Phys, Moscow 119991, Russia
[2] Moscow MV Lomonosov State Univ, Moscow 119991, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B | 2017年 / 11卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
Rydberg states of the NO molecule; interaction with valence and dissociative configurations; external laser field; radiation collision matrix; resonance states; CONFIGURATION-INTERACTION CALCULATIONS; BASIS-SET; PLUS O;
D O I：
10.1134/S1990793117010250
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
A method taking into account valence (non-Rydberg) and dissociative configurations has been developed for calculation of potential energy surfaces of the NO molecule in an intense IR radiation field. The resonance rovibronic structure of the Rydberg molecule-laser field quantum system has been analyzed within the steady-state formalism of the radiation collision matrix using multi-channel quantum defect theory. Special conditions for field control of predissociation involving intermediate Rydberg and valence states have been formulated.
引用
收藏
页码：77 / 82
页数：6
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