Homogeneous catalytic transfer dehydrogenation of alkanes with a group 10 metal center

被引：18
|
作者：
Khaskin, Eugene [1 ]
Lew, Daniel L. [1 ]
Pal, Shrinwantu [1 ]
Vedernikov, Andrei N. [1 ]
机构：
[1] Univ Maryland Chem & Biochem, College Pk, MD 20742 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 41期
基金：
美国国家科学基金会;
关键词：
H-BOND-CLEAVAGE; DIHYDROGEN ATMOSPHERE; IRIDIUM COMPLEXES; BETA-DIIMINATE; ACTIVATION; MECHANISM; HYDROGEN;
D O I：
10.1039/b913319d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Unambiguous catalytic homogeneous alkane transfer dehydrogenation was observed with a group 10 metal complex catalyst, LPtII(cyclo-C6H10)H, supported by a lipophilic dimethyl-di(4-tert-butyl-2-pyridyl)borate anionic ligand and tert-butylethene as the sacrificial hydrogen acceptor.
引用
收藏
页码：6270 / 6272
页数：3
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