Homogeneous catalytic transfer dehydrogenation of alkanes with a group 10 metal center

被引：18

作者：

Khaskin, Eugene ^{[1
]}

Lew, Daniel L. ^{[1
]}

Pal, Shrinwantu ^{[1
]}

Vedernikov, Andrei N. ^{[1
]}

机构：

[1] Univ Maryland Chem & Biochem, College Pk, MD 20742 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 41期

基金：

美国国家科学基金会;

关键词：

H-BOND-CLEAVAGE; DIHYDROGEN ATMOSPHERE; IRIDIUM COMPLEXES; BETA-DIIMINATE; ACTIVATION; MECHANISM; HYDROGEN;

D O I：

10.1039/b913319d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Unambiguous catalytic homogeneous alkane transfer dehydrogenation was observed with a group 10 metal complex catalyst, LPtII(cyclo-C6H10)H, supported by a lipophilic dimethyl-di(4-tert-butyl-2-pyridyl)borate anionic ligand and tert-butylethene as the sacrificial hydrogen acceptor.

引用

页码：6270 / 6272

页数：3

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