Multifunctional metal-organic frameworks constructed from meta-benzenedicarboxylate units

被引：465
|
作者：
He, Yabing [1 ]
Li, Bin [2 ]
O'Keeffe, Michael [3 ]
Chen, Banglin [2 ]
机构：
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Jinhua 321004, Peoples R China
[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA
[3] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA
来源：
CHEMICAL SOCIETY REVIEWS | 2014年 / 43卷 / 16期
基金：
中国国家自然科学基金;
关键词：
HIGH H-2 ADSORPTION; SUPERMOLECULAR BUILDING-BLOCKS; INFINITE POLYMERIC FRAMEWORKS; PRUSSIAN BLUE ANALOGS; HYDROGEN STORAGE; CRYSTAL-STRUCTURE; METHANE STORAGE; COORDINATION POLYMERS; HIGH-CAPACITY; SURFACE-AREA;
D O I：
10.1039/c4cs00041b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Metal-organic frameworks (MOFs), also known as porous coordination polymers (PCPs), are an emerging type of porous materials which are formed by the self-assembly of metallic centers and bridging organic linkers. Design and synthesis of organic linkers are very critical to target MOFs with desired structures and properties. In this review, we summarize and highlight the recent development of porous MOFs that are constructed from the multicarboxylate ligands containing m-benzenedicarboxylate moieties, and their promising applications in gas storage and separation, heterogeneous catalysis and luminescent sensing.
引用
收藏
页码：5618 / 5656
页数：39
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