Metal-organic frameworks constructed from pentagonal antiprismatic and cuboctahedral secondary building units

被引：148
|
作者：
Vodak, DT [1 ]
Braun, ME [1 ]
Kim, J [1 ]
Eddaoudi, M [1 ]
Yaghi, OM [1 ]
机构：
[1] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 24期
关键词：
D O I：
10.1039/b108684g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two crystalline metal-organic frameworks formulated as Zn-6(NDC)(5)(OH)(2)(DMT)(2). 4DMF, MOF-48, and Zn-7(m-BDC)(6)(OH)(4)(H2O)(2). 6DMF . 4H(2)O, MOF-49, (NDC = 1,4-naphthalenedicarboxylate; m-BDC = 1,3-benzenedicarboxylate) have been synthesized and fully characterized by single crystal X-ray diffraction studies, which reveal that the frameworks are constructed from pentagonal antiprismatic (MOF-48) and cuboctahedral (MOF-49) secondary building units respectively, however, both are reticulated into 3-D structures having the B network of CaB6.
引用
收藏
页码：2534 / 2535
页数：2
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