Low temperature hydrogenation of tetralin over supported rhodium catalysts in supercritical carbon dioxide solvent

被引：20
|
作者：
Hiyoshi, Norihito
Mine, Eiichi
Rode, Chandrashekhar V.
Sato, Osamu
Shirai, Masayuki
机构：
[1] Natl Inst Adv Ind Sci & Technol, Res Ctr Compact Chem Proc, Sendai, Miyagi 9838551, Japan
[2] Natl Chem Lab, Homogeneous Catalysis Div, Pune 411008, Maharashtra, India
来源：
APPLIED CATALYSIS A-GENERAL | 2006年 / 310卷
关键词：
supercritical carbon dioxide; hydrogenation; tetralin; supported rhodium catalysts; cis-decalin; hydrogen storage;
D O I：
10.1016/j.apcata.2006.05.040
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Hydrogenation of tetralin was studied over supported rhodium catalysts in supercritical carbon dioxide solvent at 333 K. The results were compared with those in an organic solvent and under neat conditions. Higher cis-decalin yield was obtained in supercritical carbon dioxide solvent than under non-supercritical conditions. It was observed that higher hydrogen concentration at the surface in supercritical carbon dioxide solvent led to fast direct hydrogenation of tetralin to cis-decalin; the flipping of the intermediate, octalin, to give trans-decalin could be prevented. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：194 / 198
页数：5
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