Investigation of the reaction of dithiocarbamic acid salts with trimethyl orthoformate and styrene epoxide

被引：8

作者：

Halimehjani, Azim Ziyaei ^{[1
]}

Shayegan, Mojtaba Hajilou ^{[2
]}

Poshteh, Shiva Shakori ^{[3
]}

Amani, Vahid ^{[4
]}

Notash, Behrouz ^{[5
]}

Hashemi, Mohammad M. ^{[2
]}

机构：

[1] Kharazmi Univ, Fac Chem, Tehran, Iran

[2] Sharif Univ Technol, Dept Chem, Tehran, Iran

[3] Islamic Azad Univ, Pharmaceut Sci Branch IAUPS, Tehran, Iran

[4] Islamic Azad Univ, Yadegar E Imam Khomeini RAH Branch, Dept Chem, Tehran, Iran

[5] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran

来源：

TETRAHEDRON LETTERS | 2015年 / 56卷 / 51期

关键词：

Dithiocarbamate; Orthoesters; Epoxides; 4-(N,N-Dialkyldithiocarbamato)-2-dialkyliminio-1,3-dithietane; tetrafluoroborate 2-iminium-1,3-dithiolanes; ONE-POT SYNTHESIS; RADICAL POLYMERIZATION; EFFICIENT INTERMEDIATE; HIGHLY EFFICIENT; CARBON-DISULFIDE; AMINES; 3-COMPONENT; RHODANINES; COMPLEXES; THIOUREAS;

D O I：

10.1016/j.tetlet.2015.11.033

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of dithiocarbamic acid salts with trimethyl orthoformate in the presence of BF3 center dot OEt2 was investigated to give 4-(N,N-dialkyldithiocarbamato)-2-dialkyliminio-1,3-dithietane tetrafluoroborates in good yields. Additionally, a one-pot procedure for the synthesis of 2-iminium-1,3-dithiolanes from the BF3 center dot OEt2 catalyzed reaction of dithiocarbamic acid salts with styrene epoxide is described. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：7124 / 7127

页数：4

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