Investigation of the Reaction of Dithiocarbamic Acid Salts with Aromatic Aldehydes

被引：41

作者：

Halimehjani, Azim Ziyaei ^{[1
]}

Shayegan, Mojtaba Hajiloo ^{[2
]}

Hashemi, Mohammad Mahmoodi ^{[2
]}

Notash, Behrooz ^{[3
]}

机构：

[1] Tarbiat Moallem Univ, Fac Chem, Tehran, Iran

[2] Sharif Univ Technol, Dept Chem, Tehran, Iran

[3] Shahid Beheshti Univ, GC, Dept Chem, Tehran 1983963113, Iran

来源：

ORGANIC LETTERS | 2012年 / 14卷 / 15期

关键词：

ONE-POT SYNTHESIS; RADICAL POLYMERIZATION; CARBONYL-COMPOUNDS; HIGHLY EFFICIENT; PROTECTION; THIOUREAS; AGENT;

D O I：

10.1021/ol301598u

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A reaction of dithiocarbamic acid salts with carbonyl compounds was investigated for the first time In the presence of BF3 center dot OEt2. The reaction is temperature dependent and gives gem-bis(dithiocarbamates) at 35-45 degrees C as a molecule with high equivalents of dithiocarbamate groups. At lower temperatures (15-20 degrees C), the 2-iminium-1,3-dithietane is obtained as the only product. The structure of a 2-iminium-1,3-dithietane was accomplished by X-ray crystallographic analysis.

引用

页码：3838 / 3841

页数：4

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