Explosion hazard of hydrogen-air mixtures in the large volumes

被引:30
|
作者
Petukhov, V. A. [1 ]
Naboko, I. M. [1 ]
Fortov, V. E. [1 ]
机构
[1] Russian Acad Sci, Joint Inst High Temp, Moscow 127512, Russia
关键词
Hydrogen-air mixtures; Problems of safety; Shock waves; Explosion; Deflagration; Detonation; IGNITION;
D O I
10.1016/j.ijhydene.2009.02.064
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The report deals with the investigation of non-stationary combustion of hydrogen-air mixtures extremely relevant to the issues of safety. Considered are the conditions of its formation and development in the tubes, in the conic element and in the spherical 12-m diameter chamber. The report shows that at the formation of non-stationary combustion in the conic element, in its top the pressure can develop exceeding 100 MPa. It is also shown that in large closed volumes non-stationary combustion can develop from a small energy source, in contrast to detonation for its stimulation in large volumes of significant power influences are required. Simultaneously, in the large closed volume a pressure can be formed by far exceeding the Chapman-Jouguet pressure in the front of stationary detonation. (C) 2009 Published by Elsevier Ltd on behalf of International Association for Hydrogen Energy.
引用
收藏
页码:5924 / 5931
页数:8
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