A highly selective fluorescent chemosensor for lead ions

被引:309
|
作者
Chen, CT [1 ]
Huang, WP [1 ]
机构
[1] Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan
关键词
D O I
10.1021/ja025710e
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A simple fluorescent chemosensor 1 exhibits a 40-fold fluorescence enhancement upon addition of lead ion and yet is insensitive to most of univalent and divalent metal ions. The high affinity of 1 toward Pb2+ presumably results from the cooperative binding behaviors of two potential metal binding sites: the dicarbonyl and the 15-monoazacrown-5 ether. Copyright © 2002 American Chemical Society.
引用
收藏
页码:6246 / 6247
页数:2
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