The X-ray structure of a protonated hypervalent silanol

被引：19
|
作者：
Bassindale, AR
Parker, DJ
Taylor, PG
Auner, N
Herrschaft, B
机构：
[1] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England
[2] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 07期
关键词：
D O I：
10.1039/a909504g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Careful hydrolysis of a pentacoordinate chlorosilane gives a pentacoordinate protonated silanol that resembles the intermediate in the aqueous hydrolysis of silanes.
引用
收藏
页码：565 / 566
页数：2
相关论文
共 50 条
  • [21] X-RAY CRYSTAL-STRUCTURE ANALYSIS OF PROTONATED PHENYL-(T-BUTYL)-PHOSPHINIC AMIDE
    WONGNG, W
    NYBURG, SC
    MODRO, TA
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (04) : 195 - 196
  • [22] X-RAY STRUCTURE OF DIBROMOCANNABICYCLOL - STRUCTURE OF BICYCLOMAHANIMBINE
    BEGLEY, MJ
    CLARKE, DG
    CROMBIE, L
    WHITING, DA
    JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (22): : 1547 - +
  • [23] Electronic Fingerprint of the Protonated Imidazole Dimer Probed by X-ray Absorption Spectroscopy
    Das, Sambit K.
    Winghart, Marc-Oliver
    Han, Peng
    Rana, Debkumar
    Zhang, Zhuang-Yan
    Eckert, Sebastian
    Fondell, Mattis
    Schnappinger, Thomas
    Nibbering, Erik T. J.
    Odelius, Michael
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2024, 15 (05): : 1264 - 1272
  • [24] X-RAY STUDY OF FRACTURE STRUCTURE
    GEORGIYEV, MN
    STROK, LP
    FIZIKA METALLOV I METALLOVEDENIE, 1982, 54 (06): : 1161 - 1165
  • [25] X-RAY STRUCTURE OF TETRAMETHYL THIOPHENETETRACARBOXYLATE
    BRIDSON, JN
    SCHRIVER, MJ
    ZHU, SG
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1994, 24 (12) : 801 - 803
  • [26] X-RAY STRUCTURE ANALYSIS OF NEOPHORBOL
    HOPPE, W
    BRANDL, F
    STRELL, I
    ROHRL, M
    GASSMANN, I
    HECKER, E
    BARTSCH, H
    KREIBICH, G
    VONSZCZE.C
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1967, 6 (09) : 809 - &
  • [27] X-ray structure of tricyclohexylmethyl chloride
    Gillies, DG
    Luff, S
    Smith, GW
    Sutcliffe, LH
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1996, 26 (08) : 539 - 542
  • [28] X-RAY DIFFRACTION AND STRUCTURE OF WATER
    BOL, W
    JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1968, 1 : 234 - &
  • [29] X-RAY STUDY OF STRUCTURE OF MESITYLMETHYLSULPHONE
    KOSTURKI.Z
    STRUCHKO.YT
    BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1967, 15 (12): : 573 - &
  • [30] X-RAY STUDIES ON STRUCTURE OF TERFERROCENYL
    KALUSKI, Z
    STRUCHKO.YT
    BULLETIN DE L ACADEMIE POLONAISE DES SCIENCES-SERIE DES SCIENCES CHIMIQUES, 1966, 14 (09): : 607 - &
12345