The X-ray structure of a protonated hypervalent silanol

被引：19
|
作者：
Bassindale, AR
Parker, DJ
Taylor, PG
Auner, N
Herrschaft, B
机构：
[1] Open Univ, Dept Chem, Milton Keynes MK7 6AA, Bucks, England
[2] Univ Frankfurt, Inst Anorgan Chem, D-60439 Frankfurt, Germany
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 07期
关键词：
D O I：
10.1039/a909504g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Careful hydrolysis of a pentacoordinate chlorosilane gives a pentacoordinate protonated silanol that resembles the intermediate in the aqueous hydrolysis of silanes.
引用
收藏
页码：565 / 566
页数：2
相关论文
共 50 条
  • [1] X-RAY STUDY OF COMPOUNDS OF HYPERVALENT SILICON
    Zelbst, E. A.
    Kashaev, A. A.
    Demidov, M. P.
    Voronkov, M. G.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1999, 55 : 438 - 438
  • [2] X-ray Induced Fragmentation of Protonated Cystine
    Gopakumar, Geethanjali
    Svensson, Pamela H. W.
    Granas, Oscar
    Brena, Barbara
    Schwob, Lucas
    Unger, Isaak
    Saak, Clara-Magdalena
    Timm, Martin
    Buelow, Christine
    Kubin, Markus
    Zamudio-Bayer, Vicente
    Lau, J. Tobias
    von Issendorff, Bernd
    Abid, Abdul R.
    Lindblad, Andreas
    Danielsson, Emma
    Koerfer, Ebba
    Caleman, Carl
    Bjorneholm, Olle
    Lindblad, Rebecka
    JOURNAL OF PHYSICAL CHEMISTRY A, 2022, 126 (09): : 1496 - 1503
  • [3] The local structure of protonated water from x-ray absorption and density functional theory
    Cavalleri, Matteo
    Naslund, Lars-Ake
    Edwards, David C.
    Wernet, Philippe
    Ogasawara, Hirohito
    Myneni, Satish
    Ojamae, Lars
    Odelius, Michael
    Nilsson, Anders
    Pettersson, Lars G. M.
    JOURNAL OF CHEMICAL PHYSICS, 2006, 124 (19):
  • [4] THE X-RAY STRUCTURES OF SOME PROTONATED CYCLOPROPYL KETONES
    KOSTYK, MD
    CHILDS, RF
    MAHENDRAN, M
    FAGGIANI, R
    LOCK, CJL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 195 : 71 - ORGN
  • [5] X-RAY STRUCTURE
    不详
    NATURE-PHYSICAL SCIENCE, 1971, 234 (51): : 142 - &
  • [6] Preparation, X-ray Structure, and Reactivity of 2-lodylpyridines: Recyclable Hypervalent lodine(V) Reagents
    Yoshimura, Akira
    Banek, Christopher T.
    Yusubov, Mekhman S.
    Nemykin, Victor N.
    Zhdankin, Viktor V.
    JOURNAL OF ORGANIC CHEMISTRY, 2011, 76 (10): : 3812 - 3819
  • [7] X-ray crystal structures of a benzonorbornenyl cation and of a protonated benzonorbornenol
    Laube, T
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (35) : 10904 - 10912
  • [8] Self-Assembly of the Hexabromorhenate(IV) Anion with Protonated Benzotriazoles: X-ray Structure and Magnetic Properties
    Martinez-Lillo, Jose
    Kong, John
    Julve, Miguel
    Brechin, Euan K.
    CRYSTAL GROWTH & DESIGN, 2014, 14 (11) : 5985 - 5990
  • [9] PERFORMANCE OF INSPECTION OF X-RAY STRUCTURE AND X-RAY SPECTROSCOPY APPLIANCES
    ANGER, K
    KONIG, W
    ISOTOPENPRAXIS, 1977, 13 (06): : 222 - 224
  • [10] X-RAY STRUCTURE OF DIPHENYLCYCLOPROPENETHIONE
    REED, LL
    SCHAEFER, JP
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (09) : 528 - &
12345