Palladium-catalyzed regio- and diastereoselective allylic alkylation with azlactones using triphenylarsine

被引：16
|
作者：
Kawatsura, Motoi [1 ]
Ikeda, Daiji
Ishii, Tamiko
Komatsu, Yuji
Uenishi, Junichi
机构：
[1] Tottori Univ, Fac Engn, Dept Mat Sci, Tottori 6808552, Japan
[2] Kyoto Pharmaceut Univ, Kyoto 6078412, Japan
来源：
SYNLETT | 2006年 / 15期
关键词：
palladium catalysis; triphenylarsine; regioselectivity; diastereoselectivity; alkylations;
D O I：
10.1055/s-2006-950400
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The palladium-catalyzed regio- and diastereoselective allylic alkylation of (R)-2-acetoxy-4-phenyl-3-butene with azlactones using AsPh3 successfully occurred. The stereochemistries were highly controlled, and the reaction produced a coupling product which possessed vicinal chiral quaternary and tertiary carbon centers.
引用
收藏
页码：2435 / 2438
页数：4
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