H2O2/SOCl2: a useful reagent system for the conversion of thiocarbonyls to carbonyl compounds

被引：35
|
作者：
Bahrami, Kiumars [1 ,2 ]
Khodaei, Mohammad M. [1 ,2 ]
Farrokhi, Azita [1 ]
机构：
[1] Razi Univ, Dept Chem, Kermanshah 67149, Iran
[2] Razi Univ, NNRC, Kermanshah 67149, Iran
来源：
TETRAHEDRON | 2009年 / 65卷 / 36期
关键词：
MICROWAVE IRRADIATION; ORGANOPHOSPHORUS COMPOUNDS; OXIDATIVE AMIDATION; SELECTIVE OXIDATION; HYDROGEN-PEROXIDE; EFFICIENT METHOD; AMIDES; ALDEHYDES; TRANSFORMATION; THIOKETONES;
D O I：
10.1016/j.tet.2009.06.110
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The H2O2/SOCl2 reagent system has been used as a new and efficient reagent for deprotection of thiocarbonyls to carbonyl compounds. The salient features of this protocol are short reaction times, good chemoselectivity, clean reaction profiles, and simple work-up that preclude the use of toxic solvents. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7658 / 7661
页数：4
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