Catalytic selective ring opening of methylcyclopentane in the presence of CO2

被引：7
|
作者：
Upare, Dipali P. [1 ,2 ]
Lee, Chul Wee [1 ,2 ]
机构：
[1] Korea Res Inst Chem Technol, Div Green Chem & Engn Res, Taejon 305600, South Korea
[2] Univ Sci & Technol, Sch Sci, Taejon 305333, South Korea
来源：
FUEL PROCESSING TECHNOLOGY | 2014年 / 126卷
关键词：
Methylcyclopentane; Selective ring opening; Polycyclic aromatic compounds; CO2; utilization; CARBON-DIOXIDE; ZEOLITES; IR; METHYLCYCLOHEXANE; PT-IR/AL2O3; TECHNOLOGY; MECHANISMS; STRATEGIES; CONVERSION; MORDENITE;
D O I：
10.1016/j.fuproc.2014.05.010
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Simple and highly efficient approach for the utilization of carbon dioxide (CO2) in selective ring opening (SRO) of methylcyclopentane (MCP) over 0.9 wt% Ir/USY catalyst is described. Ring opening products such as n-hexane, 2-MP and 3-MP were formed during the SRO of MCP in the presence of CO2. The influence of CO2 pressure on the total conversion and ring opening (RO) product selectivity was examined, which highlights the great potential of CO2 utilization in petroleum industry for SRO process. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：243 / 248
页数：6
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