Metal-Free Microwave-Assisted Decarboxylative Elimination for the Synthesis of Olefins

被引：23
|
作者：
Wu, Shu-Wei
Liu, Jia-Li
Liu, Feng [1 ]
机构：
[1] Soochow Univ, Jiangsu Key Lab Translat Res & Therapy Neuropsych, Suzhou 215123, Jiangsu, Peoples R China
来源：
ORGANIC LETTERS | 2016年 / 18卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ALIPHATIC CARBOXYLIC-ACIDS; LIGHT PHOTOREDOX CATALYSIS; TRACELESS DIRECTING GROUPS; ALPHA-AMINO-ACIDS; ROOM-TEMPERATURE; AQUEOUS-SOLUTION; DECARBONYLATIVE DEHYDRATION; OXIDATIVE DECARBOXYLATION; H FUNCTIONALIZATION; DIRECT ARYLATION;
D O I：
10.1021/acs.orglett.5b03069
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A metal-free efficient synthesis of olefins via microwave-assisted direct decarboxylative elimination of arylacetic acids is described. This reaction, using commercially available reagent PIFA as oxidant, readily provides a variety of desired products in moderate to good yields.
引用
收藏
页码：1 / 3
页数：3
相关论文
共 50 条
  • [31] Microwave-Assisted Synthesis Cd Metal Hexagonal Nanosheets
    Sun, Yidong
    She, Houde
    Bai, Wencai
    Li, Liangshan
    Zhou, Hua
    [J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 92 (07) : 1351 - 1354
  • [32] Microwave-Assisted Synthesis of Metal-Organic Frameworks
    Klinowski, Jacek
    Almeida Paz, Filipe A.
    Silva, Patricia
    Rocha, Joao
    [J]. DALTON TRANSACTIONS, 2011, 40 (02) : 321 - 330
  • [33] Microwave-Assisted Synthesis Cd Metal Hexagonal Nanosheets
    Houde Yidong Sun
    Wencai She
    Liangshan Bai
    Hua Li
    [J]. Russian Journal of Physical Chemistry A, 2018, 92 : 1351 - 1354
  • [34] Microwave-assisted route for synthesis of nanosized metal oxides
    Lagashetty, Arunkumar
    Havanoor, Vijayanand
    Basavaraja, S.
    Balaji, S. D.
    Venkataraman, A.
    [J]. SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS, 2007, 8 (06) : 484 - 493
  • [35] MICROWAVE-ASSISTED ROUTE FOR SYNTHESIS OF NANOSIZED METAL SULPHIDES
    Mispa, K. Jacinth
    Subramaniam, P.
    Murugesan, R.
    [J]. CHALCOGENIDE LETTERS, 2010, 7 (05): : 345 - 350
  • [36] MICROWAVE-ASSISTED SYNTHESIS
    Gediz Erturk, Aliye
    Bekdemir, Yunus
    [J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2014, 189 (02) : 285 - 292
  • [37] Metal-Free Electrochemical Hydroboration of Olefins
    Yuan, Qilin
    Zhang, Xiao
    Guo, Lin
    Yang, Chao
    Xia, Wujiong
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2023, 365 (11) : 1788 - 1793
  • [38] Double decarboxylative Claisen rearrangement reactions:: microwave-assisted de novo synthesis of pyridines
    Craig, Donald
    Paina, Federica
    Smith, Stephen C.
    [J]. CHEMICAL COMMUNICATIONS, 2008, (29) : 3408 - 3410
  • [39] Synthesis of Biaryls and Aryl Ketones via Microwave-Assisted Decarboxylative Cross-Couplings
    Goossen, Lukas J.
    Zimmermann, Bettina
    Linder, Christophe
    Rodriguez, Nuria
    Lange, Paul P.
    Hartung, Jens
    [J]. ADVANCED SYNTHESIS & CATALYSIS, 2009, 351 (16) : 2667 - 2674
  • [40] Metal-free cyclopropanation of electrophilic olefins
    Batista, Gabriel
    Castro, Pedro
    Carpanez, Arthur
    Horta, Bruno
    Amarante, Giovanni
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
12345