Metal-Free Microwave-Assisted Decarboxylative Elimination for the Synthesis of Olefins

被引：23
|
作者：
Wu, Shu-Wei
Liu, Jia-Li
Liu, Feng [1 ]
机构：
[1] Soochow Univ, Jiangsu Key Lab Translat Res & Therapy Neuropsych, Suzhou 215123, Jiangsu, Peoples R China
来源：
ORGANIC LETTERS | 2016年 / 18卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ALIPHATIC CARBOXYLIC-ACIDS; LIGHT PHOTOREDOX CATALYSIS; TRACELESS DIRECTING GROUPS; ALPHA-AMINO-ACIDS; ROOM-TEMPERATURE; AQUEOUS-SOLUTION; DECARBONYLATIVE DEHYDRATION; OXIDATIVE DECARBOXYLATION; H FUNCTIONALIZATION; DIRECT ARYLATION;
D O I：
10.1021/acs.orglett.5b03069
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A metal-free efficient synthesis of olefins via microwave-assisted direct decarboxylative elimination of arylacetic acids is described. This reaction, using commercially available reagent PIFA as oxidant, readily provides a variety of desired products in moderate to good yields.
引用
收藏
页码：1 / 3
页数：3
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