X-ray crystal structures of [Bi(C2H2N2S3)(SCN)(3)] (1) and Cs2K[Bi(SCN)(6)] (2). An unusual pentagonal-pyramidal coordination of Bi-III in (1)

被引：5

作者：

Sieron, L ^{[1
]}

BukowskaStrzyzewska, M ^{[1
]}

Cyganski, A ^{[1
]}

Turek, A ^{[1
]}

机构：

[1] TECH UNIV LODZ,INST GEN & ECOL CHEM,PL-90924 LODZ,POLAND

来源：

POLYHEDRON | 1996年 / 15卷 / 22期

关键词：

Bi-III stereochemistry; thiocyanato Bi-III complexes; unusual pentagonal-pyramidal Bi-III coordination; isoperthiocyanic acid; X-ray crystal structures;

D O I：

10.1016/0277-5387(96)00148-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new complex of Bi(SCN)(3) with the isoperthiocyanic acid: [Bi(C2H2N2S3)(SCN)(3)] (1) has been obtained during the attempted recrystallization of Dy[Bi(SCN)(6)]. 6H(2)O from HClO4. Compound (1) and CsK[Bi(SCN)(6)](2) have been investigated by X-ray crystallography. The unusual shape of deformed pentagonal pyramidal coordination of Bi-III in (1) and typical octahedral coordination in (2) have been observed. The analysis of Bi--S and Bi--N bond lengths in home and hetero-ligand thiocyanato Bi-III complexes of different coordination numbers is made on the basis of the bond's valences, computed from our literature and experimental data. The role of the Bi-III lone electron pair on the shape of Bi-III coordination polyhedra is considered. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：3923 / 3931

页数：9

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