Structural and magnetic properties of Ca1.5La0.5FeMoO6 perovskite at high pressures

被引：2

作者：

Burzo, E. ^{[1
]}

Kozlenko, D. P. ^{[2
]}

Dang, N. T. ^{[3
]}

Kichanov, S. E. ^{[2
]}

Golosova, N. O. ^{[2
]}

机构：

[1] Univ Babes Bolyai, Fac Phys, Cluj Napoca 400085, Romania

[2] Joint Inst Nucl Res, Frank Lab Neutron Phys, Dubna 141980, Russia

[3] Duy Tan Univ, Inst Res & Dev, Da Nang 550000, Vietnam

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2016年 / 664卷

基金：

俄罗斯基础研究基金会;

关键词：

Perovskite; Magnetic properties; Neutron diffraction; Pressure study; ELECTRICAL-PROPERTIES; A(2)FEMOO(6); TRANSPORT; SR2FEMOO6; STABILITY; CA;

D O I：

10.1016/j.jallcom.2015.12.254

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Neutron diffraction measurements were made under pressure on Ca1.5La0.5FeMoO6 double perovskite. The monoclinic P2(1)/n structure remains stable up to 5.7 GPa. The ordered magnetic moments at B(Fe) sites increase with pressure, while those at B'(Mo) ones are nearly pressure independent. The magnetic properties determined by neutron diffraction, at normal pressure, are compared with those obtained from magnetic measurements. The sites occupancies and valence states of Fe and Mo cations, when increasing pressure, have been analysed and correlated with the structure parameters. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：363 / 368

页数：6

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