Effect of magnesium chloride hexahydrate on thermal and mechanical properties of starch/PVA films

被引：7
|
作者：
Jiang, X. [1 ]
Dai, H. [1 ]
Zhang, X. [1 ]
机构：
[1] Sichuan Univ, Polymer Res Inst, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
来源：
PLASTICS RUBBER AND COMPOSITES | 2015年 / 44卷 / 08期
基金：
中国国家自然科学基金;
关键词：
Starch; Poly(vinyl alcohol); Plasticiser; Magnesium chloride hexahydrate; Mechanical properties; THERMOPLASTIC STARCH; POLY(VINYL ALCOHOL); POLYVINYL-ALCOHOL; SURFACE CHARACTERIZATION; MIXED PLASTICIZER; BLENDS; GLYCEROL; WATER; POLYMERIZATION; CRYSTALLINITY;
D O I：
10.1179/1743289815Y.0000000004
中图分类号：
TB33 [复合材料];
学科分类号：
摘要：
Starch/poly(vinyl alcohol) (PVA) blend films were prepared from the aqueous solutions containing starch, PVA and magnesium chloride hexahydrate (MgCl2 center dot 6H(2)O). The interaction between MgCl2 center dot 6H(2)O and starch/PVA was studied by Fourier transform infrared spectroscopy. The plasticising effect of MgCl2 center dot 6H(2)O on starch/PVA film was studied by scanning electron microscopy (SEM), X-ray diffraction, thermogravimetric analysis, dynamic mechanical analysis and tensile testing respectively. The water content of starch/PVA films increased with the content of MgCl2 center dot 6H(2)O. The absorbed water can act as the plasticiser for starch/PVA film. The crystals of starch and PVA were destroyed, and the crystallinity of starch/PVA film decreased with the plasticising effect of MgCl2 center dot 6H(2)O and water. SEM micrographs showed that the compatibility between starch and PVA improved with the addition of MgCl2 center dot 6H(2)O. The toughness of starch/PVA film increased with the content of MgCl2 center dot 6H(2)O.
引用
收藏
页码：299 / 305
页数：7
相关论文
共 50 条
  • [31] The effect of crosslinking agents on the corn starch acetates and PVA biodegradable films properties
    Zhang, Guang-Hua
    Zhou, Xiao-Feng
    Lai, Zhi-Chao
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2007, 23 (06): : 164 - 168
  • [32] Thermal characteristics of magnesium nitrate hexahydrate and magnesium chloride hexahydrate mixture as a phase change material for effective utilization of urban waste heat
    Nagano, K
    Ogawa, K
    Mochida, T
    Hayashi, K
    Ogoshi, H
    APPLIED THERMAL ENGINEERING, 2004, 24 (2-3) : 221 - 232
  • [33] Effect of gelatinization and additives on morphology and thermal behavior of corn starch/PVA blend films
    Luo, Xuegang
    Li, Jiwei
    Lin, Xiaoyan
    CARBOHYDRATE POLYMERS, 2012, 90 (04) : 1595 - 1600
  • [34] Comparative studies of starch blends on the properties of PVA films
    Phattarateera, Supanut
    Xin, Li
    Amphong, Chananon
    Limsamran, Voranon
    Threepopnatkul, Poonsub
    CARBOHYDRATE POLYMER TECHNOLOGIES AND APPLICATIONS, 2023, 6
  • [35] Properties of hydrophobic enhanced biodegradable starch/PVA films
    Key Laboratory of Aids Chemistry and Technology for Light Chemical Industry, Shaanxi University of Science and Technology, Xi'an 710021, China
    Nongye Gongcheng Xuebao, 2009, 1 (181-184):
  • [36] Fast thermal cycling of acetanilide and magnesium chloride hexahydrate for indoor solar cooking
    El-Sebaii, A. A.
    Al-Amir, S.
    Al-Marzouki, F. M.
    Faidah, Adel S.
    Al-Ghamdi, A. A.
    Al-Heniti, S.
    ENERGY CONVERSION AND MANAGEMENT, 2009, 50 (12) : 3104 - 3111
  • [37] Study on the synthesis and thermal properties of magnesium chloride hexahydrate–magnesium sulfate heptahydrate–activated carbon phase change heat storage materials
    Xiaotian Yang
    Liangyu Shen
    Qiangbin Yang
    Kezhen Wang
    Cailong Wang
    Applied Physics A, 2021, 127
  • [38] Mechanical, thermal, and barrier properties of starch films incorporated with chitosan nanoparticles
    Shapi'i, Ruzanna Ahmad
    Othman, Siti Hajar
    Basha, Roseliza Kadir
    Naim, Mohd Nazli
    NANOTECHNOLOGY REVIEWS, 2022, 11 (01) : 1464 - 1477
  • [39] Influence of Plasticizers Concentration on Thermal, Mechanical, and Physicochemical Properties on Starch Films
    Sirbu, Elena-Emilia
    Dinita, Alin
    Tanase, Maria
    Portoaca, Alexandra-Ileana
    Bondarev, Andreea
    Enascuta, Cristina-Emanuela
    Calin, Catalina
    PROCESSES, 2024, 12 (09)
  • [40] Thermal properties of a new type of calcium chloride hexahydrate-magnesium chloride hexahydrate/expanded graphite composite phase change material and its application in photovoltaic heat dissipation
    Zhang, Yongyichuan
    Zhang, Xuelai
    SOLAR ENERGY, 2020, 204 : 683 - 695
12345