Sodium Carboxymethylcellulose Derived Oxygen-Rich Porous Carbon Anodes for High-Performance Lithium/Sodium-Ion Batteries

被引：29
|
作者：
Zhang, Yongzhi [2 ]
Meng, Yan [1 ]
Wang, Yujue [2 ]
Chen, Li [3 ]
Guo, Yong [4 ]
Xiao, Dan [1 ,4 ]
机构：
[1] Sichuan Univ, Coll Chem Engn, 24 South Sect 1,Yihuan Rd, Chengdu 610065, Peoples R China
[2] Sichuan Univ, Inst New Energy & Low Carbon Technol, 24 South Sect 1,Yihuan Rd, Chengdu 610065, Peoples R China
[3] Sichuan Univ, Analyt & Testing Ctr, 24 South Sect 1,Yihuan Rd, Chengdu 610065, Peoples R China
[4] Sichuan Univ, Coll Chem, 24 South Sect 1,Yihuan Rd, Chengdu 610065, Peoples R China
来源：
CHEMELECTROCHEM | 2017年 / 4卷 / 03期
基金：
中国国家自然科学基金;
关键词：
battery anodes; carboxymethylcellulose; lithium-ion batteries; mesoporous materials; structure-activity relationships; ORDERED MESOPOROUS CARBON; RATE CAPABILITY; HARD CARBON; LI-ION; NITROGEN; CAPACITY; NA; NANOSHEETS; CELLULOSE; STORAGE;
D O I：
10.1002/celc.201600577
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Sodium carboxymethylcellulose (CMC), which contains large amounts of carboxymethyl and hydroxy groups, has been used as an oxygen-containing carbon precursor to prepare oxygen-rich porous carbon (OPC) in a silica-template process. CMC can be mixed homogeneously with the silica template because of its excellent water solubility and viscosity, which is one of the key reasons for the successful preparation of OPC. The obtained OPC possesses some micropores, many mesopores with different sizes, a large specific surface area of 1792.6m(2)g(-1), and a high oxygen content of 8.63wt%, and exhibits superb dual functionality as anodes for lithium-ion and sodium-ion batteries.
引用
收藏
页码：500 / 507
页数：8
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