Crystal structure and magnetic property of heteronuclear copper-lanthanum carboxylate complex

被引：0
|
作者：
Wu, B [1 ]
Lu, WM [1 ]
Zheng, XM [1 ]
机构：
[1] Zhejiang Univ, Inst Catalysis, Hangzhou 310028, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2002年 / 20卷 / 09期
关键词：
copper; lanthanum; heteronuclear; crystal structure; magnetic property;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title Complex, [CuLaL5 (phen) (C2H5OH)](2) (where L = alpha-methylacrylato; Phen = 1, 10-phenanthroline), has been Prepared and Its structure has been determined by X-ray diffraction analysis. The complex crystallizes in triclinic system with space group P (1) over bar. Crystal data: a = 1.2725 (3) nm, b = 1.4421(4) nm, c = 1.2109(2) nm, alpha = 109.48(2)degrees, beta = 115.26(2)degrees, gamma = 66.42(2)degrees. The complex is a discrete tetranuclear CuLaLaCa molecule bridged by alpha-methylacrylato groups. Magnetic property of the complex was also measured and discussed.
引用
收藏
页码：846 / 850
页数：5
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