Cu2O-loaded TiO2 heterojunction composites for enhanced photocatalytic H2 production

被引:33
|
作者
Chen, Jun-Li [1 ]
Liu, Ming-Ming [1 ]
Xie, Shi-Yu [1 ]
Yue, Li-Juan [1 ]
Gong, Fei-Long [1 ]
Chai, Kai-Ming [1 ]
Zhang, Yong-Hui [1 ]
机构
[1] Zhengzhou Univ Light Ind, Coll Mat & Chem Engn, Collaborat Innovat Ctr Environm Pollut Control &, Zhengzhou 450002, Peoples R China
关键词
Cu2O; TiO2; H(2)production; Heterojunction; Photocatalysis; CU2O; HETEROSTRUCTURE; NANOPARTICLES; EVOLUTION; OXIDATION; SHELLS;
D O I
10.1016/j.molstruc.2021.131294
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Cu2O/TiO2 heterogeneous materials were fabricated via simple hydrothermal and physical mixing processes to investigate the photocatalytic H-2 production performance. The morphology evolution of Cu2O was systematically explored by adjusting the amount of chemical reagents. The CT-70 (the additive amount of TiO2 was 70 wt%) exhibited superior photocatalytic activity with H-2 production of 8.33 mmol g(-1) in 6 h, which was about 416 and 49-fold more elevated those of Cu2O and TiO2. The enhancement of H-2 generation was ascribed to the proper band gap structure and the heterojunction between Cu2O and TiO2. This work provides a strategy for the simple preparation of composite materials with high photocatalytic activity. (C) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数:7
相关论文
共 50 条
  • [21] Enhanced Photoelectrochemical Properties of Cu2O-loaded Short TiO2 Nanotube Array Electrode Prepared by Sonoelectrochemical Deposition
    Yanbiao Liu
    Haibin Zhou
    Jinhua Li
    Hongchong Chen
    Di Li
    Baoxue Zhou
    Weimin Cai
    Nano-Micro Letters, 2010, (04) : 277 - 284
  • [22] Enhanced Photocatalytic H2 Production in Core-Shell Engineered Rutile TiO2
    Yang, Yongqiang
    Liu, Gang
    Irvine, John T. S.
    Cheng, Hui-Ming
    ADVANCED MATERIALS, 2016, 28 (28) : 5850 - +
  • [23] Enhanced Photoelectrochemical Properties of Cu2O-loaded Short TiO2 Nanotube Array Electrode Prepared by Sonoelectrochemical Deposition
    Liu, Yanbiao
    Zhou, Haibin
    Li, Jinhua
    Chen, Hongchong
    Li, Di
    Zhou, Baoxue
    Cai, Weimin
    NANO-MICRO LETTERS, 2010, 2 (04) : 277 - 284
  • [24] The Role of Surface Texture on the Photocatalytic H2 Production on TiO2
    Pellegrino, Francesco
    Sordello, Fabrizio
    Minella, Marco
    Minero, Claudio
    Maurino, Valter
    CATALYSTS, 2019, 9 (01)
  • [25] Effect of temperature on the photocatalytic production of H2 on Pt/TiO2
    Kim, Gonu
    Kim, Hyoung-Il
    Choi, Wonyong
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [26] Active hydrogen species on TiO2 for photocatalytic H2 production
    Wu, Zongfang
    Zhang, Wenhua
    Xiong, Feng
    Yuan, Qing
    Jin, Yuekang
    Yang, Jinlong
    Huang, Weixin
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2014, 16 (15) : 7051 - 7057
  • [27] Photocatalytic H2 production from ethanol over Au/TiO2 and Ag/TiO2
    Jovic, Vedran
    Hsieh, Pei-Huan
    Chen, Wan-Ting
    Sun-Waterhouse, Dongxiao
    Soehnel, Tilo
    Waterhouse, Geoffrey I. N.
    INTERNATIONAL JOURNAL OF NANOTECHNOLOGY, 2014, 11 (5-8) : 686 - 694
  • [28] Oxygen vacancies in concave cubes Cu2O-reduced graphene oxide heterojunction with enhanced photocatalytic H2 production
    Zhang, Yong-Hui
    Cai, Xiao-Li
    Guo, Dong-Yang
    Zhang, Hui-Jing
    Zhou, Ning
    Fang, Shao-Ming
    Chen, Jun-Li
    Zhang, Hao-Li
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (07) : 7182 - 7193
  • [29] Ionothermal synthesis of TiO2 nanoparticles for enhanced photocatalytic H2 generation
    Nagaraju, G.
    Udayabhanu
    Shubha, J. P.
    Manjunath, K.
    Dupont, J.
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2018, 43 (08) : 4028 - 4035
  • [30] Oxygen vacancies in concave cubes Cu2O-reduced graphene oxide heterojunction with enhanced photocatalytic H2 production
    Yong-Hui Zhang
    Xiao-Li Cai
    Dong-Yang Guo
    Hui-Jing Zhang
    Ning Zhou
    Shao-Ming Fang
    Jun-Li Chen
    Hao-Li Zhang
    Journal of Materials Science: Materials in Electronics, 2019, 30 : 7182 - 7193