Three-Dimensional Self-Penetrated 4-Connected Network derived from a Three-Interpenetrating 63-hcb Two-Dimensional Subnet: Synthesis, Crystal Structure, and Luminescent Property

被引：2

作者：

Jia, Huali ^{[1
]}

Li, Yanxia ^{[1
]}

机构：

[1] Zhoukou Normal Univ, Dept Chem, Zhoukou 466000, Henan, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 07期

关键词：

Topology; Zinc; Crystal structure; Coordination polymers; Luminescence; COORDINATION POLYMERS; 3D NETS; FRAMEWORKS; CLUSTERS; DESIGN; NI; CO; CATALYSIS; 4-RINGS; 3-RINGS;

D O I：

10.1002/zaac.201300542

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The coordination polymer [Zn(bpdc)(bimb)(H2O)](n) (1) [H(2)bpdc = biphenyl-3,4'-di carboxylate, bimb = 1,4-bis(1-imidazolyl)-2,5-dimethyl benzene] was constructed under hydrothermal conditions. The structure of complex 1 was determined by single-crystal Xray diffraction analysis and further characterized by elemental analysis, XRD, IR spectroscopy, and TG analysis. Complex 1 shows an exceptional self-penetrating 4-connected net derived from a threefold interpenetrating 6(3)-hcb subnet. Furthermore, the luminescent property of complex 1 is investigated.

引用

页码：1490 / 1493

页数：4

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