Three-Dimensional Self-Penetrated 4-Connected Network derived from a Three-Interpenetrating 63-hcb Two-Dimensional Subnet: Synthesis, Crystal Structure, and Luminescent Property

被引:2
|
作者
Jia, Huali [1 ]
Li, Yanxia [1 ]
机构
[1] Zhoukou Normal Univ, Dept Chem, Zhoukou 466000, Henan, Peoples R China
来源
关键词
Topology; Zinc; Crystal structure; Coordination polymers; Luminescence; COORDINATION POLYMERS; 3D NETS; FRAMEWORKS; CLUSTERS; DESIGN; NI; CO; CATALYSIS; 4-RINGS; 3-RINGS;
D O I
10.1002/zaac.201300542
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The coordination polymer [Zn(bpdc)(bimb)(H2O)](n) (1) [H(2)bpdc = biphenyl-3,4'-di carboxylate, bimb = 1,4-bis(1-imidazolyl)-2,5-dimethyl benzene] was constructed under hydrothermal conditions. The structure of complex 1 was determined by single-crystal Xray diffraction analysis and further characterized by elemental analysis, XRD, IR spectroscopy, and TG analysis. Complex 1 shows an exceptional self-penetrating 4-connected net derived from a threefold interpenetrating 6(3)-hcb subnet. Furthermore, the luminescent property of complex 1 is investigated.
引用
收藏
页码:1490 / 1493
页数:4
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