A general and efficient palladium-catalyzed intramolecular cyclization reaction of β-brominated porphyrins

被引：64
|
作者：
Shen, Dong-Mei [1 ]
Liu, Chao [1 ]
Chen, Qing-Yun [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 17期
关键词：
D O I：
10.1021/jo0609677
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A general and efficient synthesis of fused five-membered porphyrins from the readily available beta-brominated porphyrins via palladium-catalyzed intramolecular cyclization has been developed, which can be applied for various metal complexes of beta-brominated porphyrins or free base ones and generally results in good yields of the fused five-membered porphyrins.
引用
收藏
页码：6508 / 6511
页数：4
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