Study of oxidation properties and decomposition kinetics of three-dimensional (3-D) braided carbon fiber

被引:30
|
作者
Gao, PZ [1 ]
Wang, HJ [1 ]
Jin, ZH [1 ]
机构
[1] Xian Jiaotong Univ, Sch Mat Sci & Engn, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
基金
中国国家自然科学基金;
关键词
3-D braided carbon fiber; oxidation properties; thermal analysis; oxidation kinetics and mechanism;
D O I
10.1016/j.tca.2003.11.017
中图分类号
O414.1 [热力学];
学科分类号
摘要
The XRD, SEM. isothermal oxidation-weight loss and non-isothermal thermogravimetry (TG)-differential thermogravimetry (DTG) were used to study the oxidation properties and oxidation decomposition kinetics of three-dimensional (3-D) braided carbon fiber (abbreviated as fiber). The results showed that the non-isothermal oxidation process of fiber exhibited self-catalytic characteristic. The kinetic parameters and oxidation mechanism of fiber were Studied through analyzing the TG and DTG data by differential and integral methods. The oxidation mechanism was random nucleation, the kinetic parameters were: lg A = 10.299 min(-1); E-a = 156.29 kJ mol(-1). (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:59 / 63
页数:5
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