Ionic conductivity and viscosity correlations in liquid electrolytes for incorporation into PVDF gel electrolytes

被引:94
|
作者
Southall, JP [1 ]
Hubbard, HVSA [1 ]
Johnston, SF [1 ]
Rogers, V [1 ]
Davies, GR [1 ]
McIntyre, JE [1 ]
Ward, IM [1 ]
机构
[1] UNIV LEEDS,INTERDISCIPLINARY RES CTR POLYMER SCI & TECHNOL,LEEDS LS2 9JT,W YORKSHIRE,ENGLAND
关键词
ionic conductivity; viscosity; Walden product; lithium triflate;
D O I
10.1016/0167-2738(96)00040-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The correlation between ionic conductivity and viscosity in liquid electrolytes formed by the dissolution of lithium triflate in N,N-dimethyl formamide and tetraethylene glycol dimethyl ether has been investigated. These liquid electrolytes may be incorporated in polymer gel electrolytes based on poly(vinylidene fluoride). The use of the Walden product to investigate ionic interactions is discussed.
引用
收藏
页码:51 / 60
页数:10
相关论文
共 50 条
  • [21] Performance evaluation of PVdF gel polymer electrolytes
    P. Periasamy
    K. Tatsumi
    N. Kalaiselvi
    M. Shikano
    T. Fiyieda
    Y. Saito
    T. Sakai
    M. Mizukata
    A. Kajinami
    S. Deki
    Ionics, 2002, 8 : 453 - 460
  • [22] Performance Evaluation Of PVdF Gel Polymer Electrolytes
    Periasamy, P.
    Tatsumi, K.
    Kalaiselvi, N.
    Shikano, M.
    Fiyieda, T.
    Saito, Y.
    Sakai, T.
    Mizukata, M.
    Kajinami, A.
    Deki, S.
    IONICS, 2002, 8 (5-6) : 453 - 460
  • [23] CONDUCTIVITY AND VISCOSITY OF LIQUID POLYMER ELECTROLYTES PLASTICIZED BY PROPYLENE CARBONATE AND TETRAHYDROFURAN
    CAMERON, GG
    INGRAM, MD
    SARMOUK, K
    EUROPEAN POLYMER JOURNAL, 1990, 26 (10) : 1097 - 1101
  • [24] Gelation of the organic liquid electrolytes and the conductivities as gel electrolytes
    Meng, Yabin
    Yang, Yajiang
    ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (07) : 1428 - 1433
  • [25] A comparative study of gel polymer electrolytes based on PVDF-HFP and liquid electrolytes, containing imidazolinium ionic liquids of different carbon chain lengths in DSSCs
    Suryanarayanan, Vembu
    Lee, Kun-Mu
    Ho, Wen-Hsien
    Chen, Hung-Chang
    Ho, Kuo-Chuan
    SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2007, 91 (15-16) : 1467 - 1471
  • [26] Effect of Conducting Salts in Ionic Liquid based Electrolytes: Viscosity, Conductivity, and Li-Ion Cell Studies
    Hofmann, Andreas
    Schulz, Michael
    Hanemann, Thomas
    INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2013, 8 (08): : 10170 - 10189
  • [27] Ionic Transport and Electrochemical Stability of PVDF-HFP Based Gel Polymer Electrolytes
    Rosdi, A.
    Zainol, N. H.
    Osman, Z.
    INTERNATIONAL SYMPOSIUM ON FRONTIER OF APPLIED PHYSICS (ISFAP) 2015, 2016, 1711
  • [28] Ionic conductivity in crystalline polymer electrolytes
    Zlatka Gadjourova
    Yuri G. Andreev
    David P. Tunstall
    Peter G. Bruce
    Nature, 2001, 412 : 520 - 523
  • [29] Conductivity and Morphology Correlations of Ionic-Liquid/Lithium-Salt/Block Copolymer Nanostructured Hybrid Electrolytes
    Metwalli, Ezzeldin
    Kaeppel, Maximilian V.
    Schaper, Simon J.
    Kriele, Armin
    Gilles, Ralph
    Raftopoulos, Konstantinos N.
    Mueller-Buschbaum, Peter
    ACS APPLIED ENERGY MATERIALS, 2018, 1 (02): : 666 - 675
  • [30] Study on the conductivity of molecular gel electrolytes
    Meng, YB
    Yang, YJ
    ACTA CHIMICA SINICA, 2004, 62 (16) : 1509 - 1513