A Lemieux-Johnson oxidation of shikimic acid derivatives: facile entry to small library of protected (2S,3S,4R)-2,3,4,7-tetrahydroxy-6-oxoheptanals

被引：4
|
作者：
Psotka, Miroslav [1 ]
Martinkova, Miroslava [1 ]
Gonda, Jozef [1 ]
机构：
[1] Safarik Univ, Dept Organ Chem, Inst Chem Sci, Moyzesova 11, Kosice 04001, Slovakia
来源：
CHEMICAL PAPERS | 2017年 / 71卷 / 04期
关键词：
Shikimic acid; Lemieux-Jonson oxidation; 6-oxoheptanals; (-)-SHIKIMIC ACID; TRANSFORMATION; ANALOGS;
D O I：
10.1007/s11696-016-0004-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Lemieux-Johnson oxidation was employed for the cleavage of the carbon-carbon double bond of shikimic acid derivatives. Through this procedure, a series of the sixteen novel (2S,3S,4R)-2,3,4,7-tetrahydroxy-6-oxoheptanals bearing three contiguous stereocentres have been synthesized in excellent yields.
引用
收藏
页码：709 / 719
页数：11
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