Diaquabis(ethylenediamine-κ2N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate

被引：4

作者：

Yazicilar, Turan Kaya ^{[2
]}

Demir, Serkan ^{[2
]}

Ucar, Ibrahim ^{[1
]}

Kazak, Canan ^{[2
]}

机构：

[1] Ondokuz Mayis Univ, Art & Sci Fac, Dept Phys, TR-55139 Samsun, Turkey

[2] Ondokuz Mayis Univ, Art & Sci Fac, Dept Chem, TR-55139 Samsun, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷

关键词：

OXIDATION; COMPLEXES; CRYSTAL; THIOLS; LIGAND;

D O I：

10.1107/S1600536809022612

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Cu(C2H8N2)(2)](C12H6N2O4S2)center dot 1.5H(2)O, there are two half-molecules of the cationic complex in the asymmetric unit. The Cu2+ ions lie on inversion centres and are octahedrally coordinated by two ethylenediamine (en) and two aqua ligands in a typical Jahn-Teller distorted environment with the water O atoms in the axial positions. Two 2-mercaptonicotinate units (mnic) are linked by a disulfide bridge. All the ethylenediamine N-H and O-H groups form intermolecular hydrogen bonds with acceptor O and N atoms, giving rise to a three-dimensional network. One of the uncoordinated water molecules has a site occupation factor of 0.5.

引用

页码：M797 / U1024

页数：13

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