Catalytic wet air oxidation of bisphenol A solution in a batch-recycle trickle-bed reactor over titanate nanotube-based catalysts

被引：10
|
作者：
Kaplan, Renata [1 ]
Erjavec, Bostjan [1 ]
Senila, Marin [2 ]
Pintar, Albin [1 ]
机构：
[1] Natl Inst Chem, Lab Environm Sci & Engn, Ljubljana 1001, Slovenia
[2] Res Inst Analyt Instrumentat, INCDO INOE 2000, Cluj Napoca 400293, Romania
来源：
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH | 2014年 / 21卷 / 19期
关键词：
Batch-recyclereactor; BisphenolA; Catalytic wet air oxidation; Titanate nanotubes; TiO2; Trickle-bed reactor; Wastewater treatment; AQUEOUS-SOLUTIONS; PLANT EFFLUENTS; REMOVAL; SUPPORT;
D O I：
10.1007/s11356-014-3042-1
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Catalytic wet air oxidation (CWAO) is classified as an advanced oxidation process, which proved to be highly efficient for the removal of emerging organic pollutant bisphenol A (BPA) from water. In this study, BPA was successfully removed in a batch-recycle trickle-bed reactor over bare titanate nanotube-based catalysts at very short space time of 0.6 min g(CAT) g(-1). The as-prepared titanate nanotubes, which underwent heat treatment at 600 degrees C, showed high activity for the removal of aqueous BPA. Liquid-phase recycling (5- or 10-fold recycle) enabled complete BPA conversion already at 200 degrees C, together with high conversion of total organic carbon (TOC), i.e., 73 and 98 %, respectively. The catalyst was chemically stable in the given range of operating conditions for 189 h on stream.
引用
收藏
页码：11313 / 11319
页数：7
相关论文
共 41 条
  • [21] Assessment of CFD Euler-Euler method for trickle-bed reactor modelling in the catalytic wet oxidation of phenolic wastewaters
    Lopes, Rodrigo J. G.
    Quinta-Ferreira, Rosa M.
    CHEMICAL ENGINEERING JOURNAL, 2010, 160 (01) : 293 - 301
  • [22] Catalytic wet oxidation of phenol in a trickle bed reactor over a Pt/TiO2 catalyst
    Maugans, CB
    Akgerman, A
    WATER RESEARCH, 2003, 37 (02) : 319 - 328
  • [23] Study on Catalytic Wet Air Oxidation Process for Phenol Degradation in Synthetic Wastewater Using Trickle Bed Reactor
    Abid, Mohammad F.
    Alwan, Ghanim M.
    Abdul-Ridha, Lamyaa A.
    ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING, 2016, 41 (07) : 2659 - 2670
  • [24] Study on Catalytic Wet Air Oxidation Process for Phenol Degradation in Synthetic Wastewater Using Trickle Bed Reactor
    Mohammad F. Abid
    Ghanim M. Alwan
    Lamyaa A. Abdul-Ridha
    Arabian Journal for Science and Engineering, 2016, 41 : 2659 - 2670
  • [25] Catalytic wet air oxidation of phenol over CeO2-TiO2 catalyst in the batch reactor and the packed-bed reactor
    Yang, Shaoxia
    Zhu, Wanpeng
    Wang, Jianbing
    Chen, Zhengxiong
    JOURNAL OF HAZARDOUS MATERIALS, 2008, 153 (03) : 1248 - 1253
  • [26] Catalytic wet air oxidation of aqueous solution of phenol in a fixed bed reactor over Ru catalysts supported on ceria promoted MCM-41
    Mondal, Dilip Kumar
    Mondal, Chandona
    Roy, Shyamal
    RSC ADVANCES, 2016, 6 (115): : 114383 - 114395
  • [27] Catalytic wet air oxidation of coke-plant wastewater on ruthenium-based eggshell catalysts in a bubbling bed reactor
    Yang, M.
    Sun, Y.
    Xu, A. H.
    Lu, X. Y.
    Du, H. Z.
    Sun, C. L.
    Li, C.
    BULLETIN OF ENVIRONMENTAL CONTAMINATION AND TOXICOLOGY, 2007, 79 (01) : 66 - 70
  • [28] Catalytic Wet Air Oxidation of Coke-Plant Wastewater on Ruthenium-Based Eggshell Catalysts in a Bubbling Bed Reactor
    M. Yang
    Y. Sun
    A. H. Xu
    X. Y. Lu
    H. Z. Du
    C. L. Sun
    C. Li
    Bulletin of Environmental Contamination and Toxicology, 2007, 79 : 66 - 70
  • [29] Catalytic wet air oxidation of aqueous solution of 2-chlorophenol over Ru/zirconia catalysts
    Li, Ning
    Descorme, Claude
    Besson, Michele
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 71 (3-4) : 262 - 270
  • [30] Catalytic wet air oxidation of phenols over porous plate Cu-based catalysts
    Lai, Chujun
    He, Tianqu
    Li, Xuewen
    Chen, Fang
    Yue, Linhai
    Hou, Zhaoyin
    APPLIED CLAY SCIENCE, 2019, 181
12345