CO2 Photoreduction to CH4 Performance Under Concentrating Solar Light

被引:0
|
作者
Fang, XiaoXiang [1 ]
Gao, Zhihong [1 ]
Lu, Hanfeng [1 ]
Zhu, Qiulian [1 ]
Zhang, Zekai [1 ]
机构
[1] Zhejiang Univ Technol, Coll Chem Engn, Inst Chem React Engn, Hangzhou, Zhejiang, Peoples R China
来源
关键词
Engineering; Issue; 148; CO2; photoreduction; H2O; CH4; hydrocarbon; concentrating solar light; photocatalysis; CARBON-DIOXIDE; PHOTOCATALYTIC CONVERSION; WATER; REDUCTION; TIO2;
D O I
10.3791/58661
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
We demonstrate a method for the enhancement of CO2 photoreduction. As the driving force of a photocatalytic reaction is from solar light, the basic idea is to use concentration technology to raise the incident solar light intensity. Concentrating a large-area light onto a small area cannot only increase light intensity, but also reduce the catalyst amount, as well as the reactor volume, and increase the surface temperature. The concentration of light can be realized by different devices. In this manuscript, it is realized by a Fresnel lens. The light penetrates the lens and is concentrated on a disc-shaped catalyst. The results show that both the reaction rate and the total yield are efficiently increased. The method can be applied to most CO2 photoreduction catalysts, as well as to similar reactions with a low reaction rate at natural light.
引用
收藏
页数:5
相关论文
共 50 条
  • [41] Photodriven reduction of CO2 to CH4
    Fang, Baizeng
    Xing, Yalan
    Bonakdarpour, Arman
    Zhang, Shichao
    Wilkinson, David P.
    ACS Sustainable Chemistry and Engineering, 2015, 3 (10): : 2381 - 2388
  • [42] Theoretical Study on the Mechanism of Photoreduction of CO2 to CH4 on the Anatase TiO2(101) Surface
    Ji, Yongfei
    Luo, Yi
    ACS CATALYSIS, 2016, 6 (03): : 2018 - 2025
  • [43] Scalable fabrication of SnO2/eo-GO nanocomposites for the photoreduction of CO2 to CH4
    Yujia Liang
    Wei Wu
    Peng Wang
    Sz-Chian Liou
    Dongxia Liu
    Sheryl H. Ehrman
    Nano Research, 2018, 11 : 4049 - 4061
  • [44] Metal-oxygen hybridization in Agcluster/TiO2 for selective CO2 photoreduction to CH4
    Ban, Chaogang
    Wang, Yang
    Ma, Jiangping
    Feng, Yajie
    Wang, Xiaoxing
    Qin, Shijiang
    Jing, Shaojie
    Duan, Youyu
    Zhang, Min
    Tao, Xiaoping
    Gan, Liyong
    Zhou, Xiaoyuan
    CHEMICAL ENGINEERING JOURNAL, 2024, 488
  • [45] On the use of satellite-derived CH4 : CO2 columns in a joint inversion of CH4 and CO2 fluxes
    Pandey, S.
    Houweling, S.
    Krol, M.
    Aben, I.
    Rockmann, T.
    ATMOSPHERIC CHEMISTRY AND PHYSICS, 2015, 15 (15) : 8615 - 8629
  • [46] In Situ Loading of Cu Nanocrystals on CsCuCl3 for Selective Photoreduction of CO2 to CH4
    Zhao, Hai-Bing
    Huang, Jia-Nan
    Qin, Qi
    Chen, Hong-Yan
    Kuang, Dai-Bin
    SMALL, 2023, 19 (45)
  • [47] Spatially-separated redox sites enabling selective atmospheric CO2 photoreduction to CH4
    Wu, Yang
    Wu, Mingyu
    Zhu, Juncheng
    Zhang, Xiaojing
    Li, Jing
    Zheng, Kai
    Hu, Jun
    Liu, Chengyuan
    Pan, Yang
    Zhu, Junfa
    Sun, Yongfu
    Xie, Yi
    SCIENCE CHINA-CHEMISTRY, 2023, 66 (07) : 1997 - 2003
  • [48] Highly Durable and Fully Dispersed Cobalt Diatomic Site Catalysts for CO2 Photoreduction to CH4
    Wang, Jinming
    Kim, Eunhyo
    Kumar, Dharani Praveen
    Rangappa, Akkammagari Putta
    Kim, Yujin
    Zhang, Yuexing
    Kim, Tae Kyu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (06)
  • [49] Scalable fabrication of SnO2/eo-GO nanocomposites for the photoreduction of CO2 to CH4
    Liang, Yujia
    Wu, Wei
    Wang, Peng
    Liou, Sz-Chian
    Liu, Dongxia
    Ehrman, Sheryl H.
    NANO RESEARCH, 2018, 11 (08) : 4049 - 4061
  • [50] Spatially-separated redox sites enabling selective atmospheric CO2 photoreduction to CH4
    Yang Wu
    Mingyu Wu
    Juncheng Zhu
    Xiaojing Zhang
    Jing Li
    Kai Zheng
    Jun Hu
    Chengyuan Liu
    Yang Pan
    Junfa Zhu
    Yongfu Sun
    Yi Xie
    Science China(Chemistry), 2023, (07) : 1997 - 2003