High-performance, solution-processed organic thin film transistors from a novel pentacene precursor

被引:415
|
作者
Afzali, A [1 ]
Dimitrakopoulos, CD [1 ]
Breen, TL [1 ]
机构
[1] IBM Corp, Div Res, TJ Watson Res Ctr, Yorktown Hts, NY 10598 USA
关键词
D O I
10.1021/ja0266621
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Lewis acid-catalyzed Diels-Alder reaction of the organic semiconductor pentacene with N-sulfinylacetamide yields a soluble adduct. Spin-coated thin films of this adduct undergo solid-phase conversion to form thin films of pentacene at moderate temperatures. Organic thin film transistors fabricated by spin-coating this adduct, followed by thermal conversion to pentacene, exhibit the highest mobility reported to date for a solution-processed organic semiconductor. Copyright © 2002 American Chemical Society.
引用
收藏
页码:8812 / 8813
页数:2
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