Synthesis, spectroscopic and electrochemical properties of the perylene-tetrathiafulvalene dyads

被引：7

作者：

Zhang, Yu ^{[1
,2
]}

Xu, Zheng ^{[3
]}

Qiu, Hai-xia ^{[1
,2
]}

Lai, Guo-qiao ^{[3
]}

Shen, Yong-jia ^{[1
,2
]}

机构：

[1] E China Univ Sci & Technol, Adv Mat Lab, Shanghai 200237, Peoples R China

[2] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China

[3] Hangzhou Normal Univ, Minist Educ, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 310012, Zhejiang, Peoples R China

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 2009年 / 204卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Perylene; TTF; Fluorescence spectra; Intramolecular charge transfer; Electron transfer; HIGHLY FLUORESCENT; ENERGY-TRANSFER; ELECTRON; TRIADS;

D O I：

10.1016/j.jphotochem.2009.02.016

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The TTF-perylene dyads 1-3 were designed and synthesized. The absorption spectra, cyclic voltammogram (CV) of dyads and the frontier orbital calculation indicated no intramolecular charge transfer (ICT) interaction in their ground state. The fluorescence spectra and theoretical calculation of the dyads 1-3 revealed the photoinduced electron transfer (PET) interaction existed in the dyads in their excited state. The chemical oxidation implied an effective reverse electron transfer from the perylene* to the TTF2+ species. The three donor-acceptor systems could be used as models for the study of photoinduced electron transfer and reverse electron transfer process. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：32 / 38

页数：7

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