Efficient oxidative removal of 4-tert-octylphenol and 17α-ethynylestradiol from aqueous solutions using ferrate(VI)

被引：3
|
作者：
Tiwari, Diwakar [1 ]
Sailo, Lalsaimawia [1 ]
Choi, Sang-Il [2 ]
Yoon, Yi-Yong [3 ]
Lee, Seung-Mok [3 ]
机构：
[1] Mizoram Univ, Sch Phys Sci, Dept Chem, Aizawl 796004, India
[2] Kwangwoon Univ, Dept Environm Engn, Seoul 01897, South Korea
[3] Catholic Kwandong Univ, Dept Hlth & Environm, 522 Naegok Dong, Kangnung 25601, Gangwondo, South Korea
来源：
KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2017年 / 34卷 / 03期
关键词：
Ferrate(VI); 4-Tert-octylphenol; 17; alpha-Ethynylestradiol; Endocrine Disruptors; Mineralization; Background Electrolytes; DISRUPTING CHEMICALS EDCS; PERSONAL CARE PRODUCTS; POTASSIUM FERRATE(VI); WATER-TREATMENT; ENDOCRINE DISRUPTORS; RAINBOW-TROUT; BISPHENOL-A; KINETICS; DEGRADATION; PHARMACEUTICALS;
D O I：
10.1007/s11814-016-0324-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ferrate(VI) was utilized to treat micro-pollutants-4-tert-octylphenol (TOP) and 17 alpha-ethynylestradiol (EE2)-from aqueous solutions. Batch studies were conducted at various pHs (7.0 to 12.0) and concentrations of TOP/or EE2 (0.03 to 0.3mmol/L) using 0.1mmol/L ferrate(VI). Time-dependent degradation of TOP and EE2 was assessed as a function of pH and micro-pollutant concentrations and we found that significant mineralization of micro-pollutants was achieved by ferrate(VI) treatment. Second-order kinetics showed 1: 1 stoichiometry was obtained between the ferrate(VI) and TOP/or EE2. Further, the effect of several background electrolytes on degradation of TOP and EE2 by ferrate(VI) was evaluated, showing insignificant effect of degradation.
引用
收藏
页码：734 / 740
页数：7
相关论文
共 50 条
  • [21] Removal of Cr (VI) from aqueous solutions using wheat bran
    Singh, K. K.
    Hasan, S. H.
    Talat, M.
    Singh, V. K.
    Gangwar, S. K.
    CHEMICAL ENGINEERING JOURNAL, 2009, 151 (1-3) : 113 - 121
  • [22] Chitin membrane for efficient laccase immobilization and synergistic removal of 17α-ethynylestradiol from water-based solutions
    Wysokowski, Marcin
    Chmielewska, Zuzanna
    Sandomierski, Mariusz
    Zdarta, Jakub
    Jesionowski, Teofil
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2024, 282
  • [23] Development of the Larval Amphibian Growth and Development Assay: effects of chronic 4-tert-octylphenol or 17β-trenbolone exposure in Xenopus laevis from embryo to juvenile
    Haselman, Jonathan T.
    Kosian, Patricia A.
    Korte, Joseph J.
    Olmstead, Allen W.
    Iguchi, Taisen
    Johnson, Rodney D.
    Degitz, Sigmund J.
    JOURNAL OF APPLIED TOXICOLOGY, 2016, 36 (12) : 1639 - 1650
  • [24] Highly efficient removal of uranium (VI) from aqueous solutions by amino functionalized bentonite
    Xie, Jingli
    Gu, Runqiu
    Jiang, Qiao
    Cao, Shengfei
    Zhang, Qi
    Luo, Hui
    Cheng, Jianfeng
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2024, 333 (03) : 1301 - 1314
  • [25] Efficient removal of Cr(VI) from aqueous solutions by polypyrrole/natural pyrite composites
    Zhang, Fen
    Xi, Luyao
    Zhao, Meiqi
    Du, Yaguang
    Ma, Liying
    Chen, Shaohua
    Ye, Hengpeng
    Du, Dongyun
    Zhang, Tian C.
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 365
  • [26] Highly efficient removal of uranium (VI) from aqueous solutions by amino functionalized bentonite
    Jingli Xie
    Runqiu Gu
    Qiao Jiang
    Shengfei Cao
    Qi Zhang
    Hui Luo
    Jianfeng Cheng
    Journal of Radioanalytical and Nuclear Chemistry, 2024, 333 : 1301 - 1314
  • [27] Highly efficient removal of uranium (VI) from aqueous solutions using poly(acrylic acid)-functionalized microspheres
    20142317792893
    Hua, D. (dbhua_lab@suda.edu.cn), 1600, Elsevier B.V., Netherlands (253):
  • [28] Highly efficient removal of uranium (VI) from aqueous solutions using poly(acrylic acid)-functionalized microspheres
    Zhang, Shuang
    Shu, Xiaowen
    Zhou, Yuan
    Huang, Li
    Hua, Daoben
    CHEMICAL ENGINEERING JOURNAL, 2014, 253 : 55 - 62
  • [29] Removal of Cr(VI) from aqueous solutions by using activated carbon supported iron catalysts as efficient adsorbents
    Derdour, Karima
    Bouchelta, Chafia
    Naser-Eddine, Amina Khorief
    Medjram, Mohamed Salah
    Magri, Pierre
    WORLD JOURNAL OF ENGINEERING, 2018, 15 (01) : 3 - 13
  • [30] Removal of chromium (VI) from aqueous solutions using poly(4-vinyl pyridine) beads
    Arslan, Metin
    Yiǧitoǧlu, Mustafa
    Soysal, Arif
    Journal of Applied Polymer Science, 2006, 101 (05): : 2865 - 2870
12345