Triselenium dicyanide from malononitrile and selenium dioxide. One-pot synthesis of selenocyanates

被引：77
|
作者：
Kachanov, AV [1 ]
Slabko, OY [1 ]
Baranova, OV [1 ]
Shilova, EV [1 ]
Kaminskii, VA [1 ]
机构：
[1] Far Eastern Natl Univ, Dept Chem, Vladivostok 690000, Russia
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 23期
关键词：
triselenium dicyanide; selenocyanate; malononitrile;
D O I：
10.1016/j.tetlet.2004.04.071
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Triselenium dicyanide is formed by the interaction of malononitrile and selenium dioxide in dimethylsulfoxide or dimethylformamide. Addition of aromatic amines, indoles and some active methylene compounds to this reaction mixture gives the corresponding selenocyanates in one-pot. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4461 / 4463
页数：3
相关论文
共 50 条
  • [1] Synthesis of Selenocyanates and Selenoethers of Amino Pyrazoles and Amino Uracils by In Situ Triselenium Dicyanide from Malononitrile and Selenium Dioxide
    Ali, Danish
    Mondal, Nurabul
    Panday, Anoop Kumar
    Choudhury, Lokman H. H.
    ACS OMEGA, 2023, 8 (28): : 25349 - 25357
  • [2] Visible Light and Triselenium Dicyanide (TSD): New Horizons in the Synthesis of Organic Selenocyanates
    Anghinoni, Joao M.
    Ferreira, Sabrina S.
    Piquini, Paulo C.
    Iglesias, Bernardo A.
    Perin, Gelson
    Penteado, Filipe
    Lenardao, Eder J.
    CHEMISTRY-A EUROPEAN JOURNAL, 2023, 29 (59)
  • [3] ONE-POT OXIDATION AND DEHYDRATION WITH SELENIUM DIOXIDE
    PILIDIS, G
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 1987, 26 (12): : 1176 - 1176
  • [4] One-pot photoenzymatic synthesis of β-chiral malononitrile derivatives
    Fan, Xin-Yue
    Yu, Yuan
    Lin, Ru-De
    Yao, Yao
    Shi, Ming-Liang
    Li, Kun
    Yu, Xiao-Qi
    Liu, Yan-Hong
    Wang, Na
    ORGANIC CHEMISTRY FRONTIERS, 2024, 11 (18): : 5179 - 5187
  • [5] Selenocyanation of Aryl and Styryl Methyl Ketones in the Presence of Selenium Dioxide and Malononitrile: An Approach for the Synthesis of α-Carbonyl Selenocyanates
    Marpna, Ibakyntiew D.
    Wanniang, Kmendashisha
    Lipon, Tyrchain Mitre
    Shangpliang, O. Risuklang
    Myrboh, Bekington
    JOURNAL OF ORGANIC CHEMISTRY, 2021, 86 (02): : 1980 - 1986
  • [6] Reaction of organic selenocyanates with hydroxides: The one-pot synthesis of dialkyl diselenides from alkyl bromides
    Krief, A
    Dumont, W
    Delmotte, C
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2000, 39 (09) : 1669 - +
  • [7] One-Pot Synthesis of CdSe Quantum Dots Using Selenium Dioxide as a Selenium Source in Aqueous Solution
    Wang, Yilin
    Yang, Hong
    Xia, Zhenyi
    Tong, Zhangfa
    Zhou, Liya
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (07): : 2316 - 2318
  • [8] Reaction of organic selenocyanates with hydroxides: The one-pot synthesis of dialkyl diselenides from alkyl bromides
    Krief, Alain
    Dumont, Willy
    Delmotte, Cathy
    Angewandte Chemie (International Edition in English), 2000, 39 (09): : 1669 - 1672
  • [9] One-pot synthesis of CdSe magic-sized nanocrystals using selenium dioxide as the selenium source compound
    Liu, Xinmei
    Jiang, Yang
    Guo, Weimin
    Lan, Xinzheng
    Fu, Fengming
    Huang, Wenyi
    Li, Lijun
    CHEMICAL ENGINEERING JOURNAL, 2013, 230 : 466 - 474
  • [10] A One-Pot Synthesis of Hydrogen and Carbon Fuels from Water and Carbon Dioxide
    Li, Fang-Fang
    Liu, Shuzhi
    Cui, Baochen
    Lau, Jason
    Stuart, Jessica
    Wang, Baohui
    Licht, Stuart
    ADVANCED ENERGY MATERIALS, 2015, 5 (07)
12345