Strong metal-support interaction between Pt and SiO2 following high-temperature reduction: a catalytic interface for propane dehydrogenation

被引：67
|
作者：
Deng, Lidan [1 ,2 ,3 ]
Miura, Hiroki [2 ,4 ,5 ]
Shishido, Tetsuya [2 ,4 ,5 ]
Hosokawa, Saburo [1 ,4 ]
Teramura, Kentaro [1 ,4 ]
Tanaka, Tsunehiro [1 ,4 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan
[2] Tokyo Metropolitan Univ, Grad Sch Urban Environm Sci, Dept Appl Chem, 1-1 Minami Osawa, Hachioji, Tokyo 1920397, Japan
[3] Wuhan Inst Technol, Sch Chem & Environm Engn, Guanggu 1st Rd, Wuhan 430073, Hubei, Peoples R China
[4] Kyoto Univ, Elements Strategy Initiat Catalysts & Batteries, Nishikyo Ku, 1-30 Goryo Ohara, Kyoto 6158245, Japan
[5] Res Ctr Hydrogen Energy Based Soc, Hachioji, Tokyo 1920397, Japan
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 51期
关键词：
D O I：
10.1039/c7cc03859c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pt/SiO2 reduced at 1073 K exhibited a high catalytic activity in propane dehydrogenation, primarily attributed to the electronic modification of Pt nanoparticles by a strong metal-support interaction ( SMSI) effect. The SMSI was observed in the Pt/SiO2 system following direct reduction in H-2 ( >773 K), and was found to increase with increasing reduction temperature.
引用
收藏
页码：6937 / 6940
页数：4
相关论文
共 50 条
  • [21] Metal-support interaction in Co/SiO2 and Co/TiO2
    Riva, R
    Miessner, H
    Vitali, R
    Del Piero, G
    APPLIED CATALYSIS A-GENERAL, 2000, 196 (01) : 111 - 123
  • [22] Metal-support interaction in Na-W-Mn/SiO2 catalyst
    Chen, H.-S.
    Niu, J.-Z.
    Zhang, B.
    Li, S.-B.
    Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 2001, 22 (05): : 814 - 816
  • [23] Oxidative Strong Metal-Support Interaction Induced by an Amorphous TiOx Seed Layer Boosts the Electrochemical Performance and High-Temperature Durability of Pt Nanocatalysts
    Seo, Jongsu
    Jeon, SungHyun
    Lee, Siwon
    Lim, Dae-Kwang
    Kim, Jun Hyuk
    Kim, Jeong Hwan
    Ahn, Sejong
    Jung, WooChul
    ACS CATALYSIS, 2022, 12 (14) : 8593 - 8600
  • [24] CATALYTIC BEHAVIOR OF POLYCRYSTALLINE PT3TI IN RELATION TO STRONG METAL-SUPPORT INTERACTION PHENOMENON
    DAUSCHER, A
    MULLER, W
    MAIRE, G
    CATALYSIS LETTERS, 1989, 2 (03) : 139 - 144
  • [25] Size-Dependent Pt-TiO2 Strong Metal-Support Interaction
    Wu, Zongfang
    Li, Yangyang
    Huang, Weixin
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2020, 11 (12): : 4603 - 4607
  • [26] PT-195 NMR-STUDY OF PT/TIO2 AND PT/SIO2 CATALYSTS - STRONG METAL SUPPORT INTERACTION
    BUCHER, JP
    VANDERKLINK, JJ
    GRAETZEL, M
    JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (04): : 1209 - 1211
  • [27] Platinum nanocrystals supported by silica, alumina and ceria:: metal-support interaction due to high-temperature reduction in hydrogen
    Penner, S
    Wang, D
    Su, DS
    Rupprechter, G
    Podloucky, R
    Schlögl, R
    Hayek, K
    SURFACE SCIENCE, 2003, 532 : 276 - 280
  • [28] PT-TI ALLOY FORMATION FROM HIGH-TEMPERATURE REDUCTION OF A TITANIA-IMPREGNATED PT CATALYST - IMPLICATIONS FOR STRONG METAL SUPPORT INTERACTION
    BEARD, BC
    ROSS, PN
    JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (26): : 6811 - 6817
  • [29] Strong Metal-Support Interactions between Pt Single Atoms and TiO2
    Han, Bing
    Guo, Yalin
    Huang, Yike
    Xi, Wei
    Xu, Jie
    Luo, Jun
    Qi, Haifeng
    Ren, Yujing
    Liu, Xiaoyan
    Qiao, Botao
    Zhang, Tao
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (29) : 11824 - 11829
  • [30] Strong metal-support interaction effect on the catalytic activity of 2D Pt nanoparticle arrays on oxide thin films
    Park, Dahee
    Kim, Sum Mi
    Kim, Sang Hoon
    Yun, Jung Yeul
    Park, Jeong Young
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
12345