Linear and non-linear optical properties of arene-Fe-Cp complexes

被引：42
|
作者：
Lambert, C
Gaschler, W
Zabel, M
Matschiner, R
Wortmann, R
机构：
[1] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany
[2] Univ Regensburg, Fak Chem & Pharm, D-93040 Regensburg, Germany
[3] Univ Kaiserslautern, Fachbereich Chem, D-67663 Kaiserslautern, Germany
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 592卷 / 01期
关键词：
non-linear optics; hyper-Rayleigh scattering; UV-vis spectroscopy; iron; chromophores; palladium-catalysed cross coupling;
D O I：
10.1016/S0022-328X(99)00497-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ionic [arene-Fe-Cp](+) fragments were used as electron accepters in combination with dimethylamino or pyridoneiminyl donors to form push-pull substituted chromophores. While a tolane derivative showed high second-order non-linear optical activity (measured by hyper-Rayleigh scattering), an analogous pyridoneimine derivative did not. With the help of an X-ray crystal structure analysis this discrepancy was traced back to a cyanine-like structure of the imine. Semiempirical INDO/S calculations support this conclusion. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：109 / 114
页数：6
相关论文
共 50 条
  • [1] Second-order non-linear optical properties of Fe(SALEN) complexes
    Chiang, W
    Vanengen, D
    Thompson, ME
    [J]. POLYHEDRON, 1996, 15 (14) : 2369 - 2376
  • [2] Molecular linear and quadratic non-linear optical properties of pentaammineruthenium complexes of coumarin dyes
    Coe, BJ
    Chadwick, G
    Houbrechts, S
    Persoons, A
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (10): : 1705 - 1711
  • [3] Linear and non-linear optical properties of amorphous Si
    Okumu, J
    Morgan, GJ
    [J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 272 (01) : 67 - 70
  • [4] Linear and non-linear optical properties of GaAs nanowires
    Satyendra Singh
    Pankaj Srivastava
    [J]. Applied Nanoscience, 2015, 5 : 273 - 279
  • [5] Linear and non-linear optical properties of GaAs nanowires
    Singh, Satyendra
    Srivastava, Pankaj
    [J]. APPLIED NANOSCIENCE, 2015, 5 (03) : 273 - 279
  • [6] Linear and Non-Linear Optical Properties of Carbon Nanotubes
    Lefrant, S.
    Buisson, J. P.
    Mevellec, J. Y.
    Baibarac, M.
    Baltog, I.
    [J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2010, 522 : 472 - 479
  • [7] Non-linear optical properties of arylfuranylpropenones
    Holla, BS
    Veerendra, B
    Indira, J
    [J]. JOURNAL OF CRYSTAL GROWTH, 2003, 252 (1-3) : 308 - 310
  • [8] Approach with DFT for non-linear optical properties of organic molecular complexes
    Kumar, Ch. Ravi Shankar
    Prasanti, Marla
    [J]. MATERIALS TODAY-PROCEEDINGS, 2022, 65 : 2551 - 2555
  • [9] Linear and non-linear optical response properties of β-enamino ketones
    Misra, Ramprasad
    Bhattacharyya, S. P.
    Maity, D. K.
    [J]. CHEMICAL PHYSICS LETTERS, 2008, 458 (1-3) : 54 - 57
  • [10] Linear and non-linear optical properties of periodic and antiperiodic dimers
    Meneghetti, M
    [J]. SYNTHETIC METALS, 1999, 102 (1-3) : 1577 - 1577
12345